Cyclopentanecarbothioic acid, 2-methylene-3-oxo-, S-phenyl ester

Base Information

Chemical Name:Cyclopentanecarbothioic acid, 2-methylene-3-oxo-, S-phenyl ester
CAS No.:96258-21-8
Molecular Formula:C13H12O2S
Molecular Weight:232.303
Hs Code.:

Synonyms:

Suppliers and Price of Cyclopentanecarbothioic acid, 2-methylene-3-oxo-, S-phenyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Cyclopentanecarbothioic acid, 2-methylene-3-oxo-, S-phenyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Cyclopentanecarbothioic acid, 2-methylene-3-oxo-, S-phenyl ester

There total 4 articles about Cyclopentanecarbothioic acid, 2-methylene-3-oxo-, S-phenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 96258-20-7
3-<(phenylthio)dichloromethyl>-2-methylenecyclopentanone

: 72581-31-8,11031-48-4
sarkomycin

: 96258-21-8
sarkomycin phenyl thio ester

Guidance literature:: With 3-methyl-4-hydroxy-5-tert-butylbenzenethiol; silver trifluoroacetate; In tetrahydrofuran; water; at 25 ℃; for 2h;
DOI:10.1021/jo00216a031

Reference yield:

: 930-30-3
cyclopent-2-enone

: 96258-21-8
sarkomycin phenyl thio ester

Guidance literature:: Multi-step reaction with 4 steps

1: 73 percent / triethylamine / ethanol / 110 h / Heating

2: 2.) CsF, benzaldehyde / 1.) CH₃CN, RT, 2 h, 2.) CH₃CN, 1 h

3: 100 percent / trichloroisocyanuric acid (Chloreal) / CCl₄ / 20 h / 5 °C

4: 80 percent / 3-tert-butyl-4-hydroxy-5-methylphenyl-sulfide, silver trifluoroacetate / H₂O; tetrahydrofuran / 2 h / 25 °C

With trichloroisocyanuric acid; 3-methyl-4-hydroxy-5-tert-butylbenzenethiol; silver trifluoroacetate; benzaldehyde; triethylamine; cesium fluoride; In tetrahydrofuran; tetrachloromethane; ethanol; water;
DOI:10.1021/jo00216a031

Reference yield:

: 76047-52-4
2-<(phenylthio)methyl>cyclopent-2-en-1-one

: 96258-21-8
sarkomycin phenyl thio ester

Guidance literature:: Multi-step reaction with 3 steps

1: 2.) CsF, benzaldehyde / 1.) CH₃CN, RT, 2 h, 2.) CH₃CN, 1 h

2: 100 percent / trichloroisocyanuric acid (Chloreal) / CCl₄ / 20 h / 5 °C

3: 80 percent / 3-tert-butyl-4-hydroxy-5-methylphenyl-sulfide, silver trifluoroacetate / H₂O; tetrahydrofuran / 2 h / 25 °C

With trichloroisocyanuric acid; 3-methyl-4-hydroxy-5-tert-butylbenzenethiol; silver trifluoroacetate; benzaldehyde; cesium fluoride; In tetrahydrofuran; tetrachloromethane; water;
DOI:10.1021/jo00216a031