Technology Process of Spiro[1,2-dioxetane-3,9'-[9H]fluorene],
4-methyl-4-(3,4,5-trimethylphenyl)-
There total 3 articles about Spiro[1,2-dioxetane-3,9'-[9H]fluorene],
4-methyl-4-(3,4,5-trimethylphenyl)- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
silver trifluoroacetate; edetate disodium;
In
dichloromethane;
for 1h;
DOI:10.1021/jo00211a003
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 30 percent / AlCl3 / CS2 / 18 h / Ambient temperature
2: AlCl3, LiAlH4 / tetrahydrofuran / 3.5 h / Ambient temperature
3: 1.) H2O2, 2.) 1,3-dibromo-5,5-dimethylhydantoin / tetrahydrofuran / 1.) from -30 deg C to RT, 95 min, 2.)RT, 4h
4: 1.3 percent / Na2EDTA, silver trifluoroacetate / CH2Cl2 / 1 h
With
lithium aluminium tetrahydride; aluminium trichloride; 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione; dihydrogen peroxide; silver trifluoroacetate; edetate disodium;
In
tetrahydrofuran; carbon disulfide; dichloromethane;
DOI:10.1021/jo00211a003
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 1.) H2O2, 2.) 1,3-dibromo-5,5-dimethylhydantoin / tetrahydrofuran / 1.) from -30 deg C to RT, 95 min, 2.)RT, 4h
2: 1.3 percent / Na2EDTA, silver trifluoroacetate / CH2Cl2 / 1 h
With
1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione; dihydrogen peroxide; silver trifluoroacetate; edetate disodium;
In
tetrahydrofuran; dichloromethane;
DOI:10.1021/jo00211a003
