nickel(2+) 12,17-diethyl-3,7-bis(3-methoxy-3-oxopropyl)-2,8,13,18-tetramethylporphine-21,22-diide

Base Information

• Chemical Name: nickel(2+) 12,17-diethyl-3,7-bis(3-methoxy-3-oxopropyl)-2,8,13,18-tetramethylporphine-21,22-diide
• CAS No.: 15892-09-8
• Molecular Formula: C₃₆H₄₀N₄NiO₄
• Molecular Weight: 651.428
• Mol file: 15892-09-8.mol

Synonyms:MesoporphyrinIX, dimethyl ester, Ni complex (6CI); Nickel, [dihydrogen7,12-diethyl-3,8,13,17-tetramethyl-2,18-porphinedipropionato(2-)]-, dimethylester (8CI); Nickel, [dihydrogen mesoporphyrin IX-ato(2-)]-, dimethyl ester(7CI); Nickel, [dimethyl 7,12-diethyl-3,8,13,17-tetramethyl-21H,23H-porphine-2,18-dipropanoato(2-)-N21,N22,N23,N24]-,(SP-4-2)-; 21H,23H-Porphine, nickel deriv.; 21H,23H-Porphine-2,18-dipropanoicacid, 7,12-diethyl-3,8,13,17-tetramethyl-, dimethyl ester, nickel complex;Mesoporphyrin IX, dimethyl ester, nickel(2+) complex; Nickel dimethylmesoporphyrin IX; Nickel mesoporphyrin IX dimethyl ester; Nickel(II)mesoporphyrin IX dimethyl ester

Chemical Property of nickel(2+) 12,17-diethyl-3,7-bis(3-methoxy-3-oxopropyl)-2,8,13,18-tetramethylporphine-21,22-diide

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Boiling Point: 995.1°Cat760mmHg
• Flash Point: 555.6°C
• Density: g/cm³

Purity/Quality:

98.5% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of nickel(2+) 12,17-diethyl-3,7-bis(3-methoxy-3-oxopropyl)-2,8,13,18-tetramethylporphine-21,22-diide

There total 5 articles about nickel(2+) 12,17-diethyl-3,7-bis(3-methoxy-3-oxopropyl)-2,8,13,18-tetramethylporphine-21,22-diide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

nickel diacetate (373-02-4,14998-37-9,33025-09-1,94044-50-5,98268-31-6) + mesoporphyrin IX DME (1263-63-4) → mesoporphyrin dimethyl ester nickel complex (15892-09-8)

Guidance literature:

In DMF (N,N-dimethyl-formamide); for 0.25h; Heating / reflux;

Reference yield: 79.0%

{dimethyl-7,12-divinyl-3,8,13,17-tetramethyl-21H,23H-porphine-2,18-dipropionato(2-)}nickel(II) (15304-70-8) → Ni(II)MESOP (15892-09-8)

Guidance literature:

With sodium tetrahydroborate; cobalt(II) chloride hexahydrate; In dichloromethane; N,N-dimethyl-formamide; at 25 ℃; for 0.416667h; Inert atmosphere;

DOI:10.1002/cjoc.201200581

Reference yield:

mesophorphyridine dimethylester + nickel diacetate (373-02-4,14998-37-9,33025-09-1,94044-50-5,98268-31-6) → Ni(II)MESOP (15892-09-8)

Guidance literature:

In dichloromethane; acetic acid; boiling 30 min; chromatography on silica gel with methylene chloride as eluant, crystallisation from methylene chloride and hexane;

upstream raw materials:

nickel diacetate

mesoporphyrin IX DME

protoporphyrin IX dimethyl ester

{dimethyl-7,12-divinyl-3,8,13,17-tetramethyl-21H,23H-porphine-2,18-dipropionato^(2-)}nickel(II)