3-Hexanone, 1-(2-methyloxiranyl)-6-(tetrahydro-2-methoxy-2H-pyran-2-yl)-

Base Information

Chemical Name:3-Hexanone, 1-(2-methyloxiranyl)-6-(tetrahydro-2-methoxy-2H-pyran-2-yl)-
CAS No.:96488-63-0
Molecular Formula:C₁₅H₂₆O₄
Molecular Weight:270.369
Hs Code.:

Synonyms:

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Chemical Property of 3-Hexanone, 1-(2-methyloxiranyl)-6-(tetrahydro-2-methoxy-2H-pyran-2-yl)-

Chemical Property:

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Technology Process of 3-Hexanone, 1-(2-methyloxiranyl)-6-(tetrahydro-2-methoxy-2H-pyran-2-yl)-

There total 11 articles about 3-Hexanone, 1-(2-methyloxiranyl)-6-(tetrahydro-2-methoxy-2H-pyran-2-yl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 96488-62-9
7-methyl-1-(tetrahydro-2-methoxypyran-2-yl)-7,8-epoxyoctan-4-ol

: 96488-63-0
7-methyl-1-(tetrahydro-2-methoxypyran-2-yl)-7,8-epoxyoctan-4-one

Guidance literature:: With dimethyl sulfoxide; triethylamine; trifluoroacetic anhydride; In dichloromethane; at -60 ℃; for 1h;

Reference yield:

: 6552-32-5
2-methylprop-2-enyl vinyl ether

: 96488-63-0
7-methyl-1-(tetrahydro-2-methoxypyran-2-yl)-7,8-epoxyoctan-4-one

Guidance literature:: Multi-step reaction with 10 steps

1: 80 percent / 24 h / 120 °C

2: 77 percent / Zn / tetrahydrofuran / 0 °C

3: 91 percent / Et₃N / tetrahydrofuran

4: 1.) n-BuLi / tetrahydrofuran / 1.) -78 deg C, 1.5 h

5: 84 percent / Amberlite IR 118

6: Et₃N / tetrahydrofuran

7: 76 percent / m-chloroperbenzoic acid, NaOAc / CH₂Cl₂ / 48 h / Ambient temperature

8: 95 percent / H₂ / 10percent Pd/C / petroleum ether

9: 95 percent / n-Bu₄N⁽¹⁺⁾F^(1-) / tetrahydrofuran

10: 72 percent / DMSO, Et₃N, trifluoroacetic acid / CH₂Cl₂ / -60 °C

With n-butyllithium; Amberlite IR 118; tetrabutyl ammonium fluoride; hydrogen; sodium acetate; dimethyl sulfoxide; triethylamine; 3-chloro-benzenecarboperoxoic acid; trifluoroacetic acid; zinc; palladium on activated charcoal; In tetrahydrofuran; dichloromethane; Petroleum ether;
DOI:10.1039/c39850000078

Reference yield:

: 3973-43-1
4-methylpent-4-enal

: 96488-63-0
7-methyl-1-(tetrahydro-2-methoxypyran-2-yl)-7,8-epoxyoctan-4-one

Guidance literature:: Multi-step reaction with 9 steps

1: 77 percent / Zn / tetrahydrofuran / 0 °C

2: 91 percent / Et₃N / tetrahydrofuran

3: 1.) n-BuLi / tetrahydrofuran / 1.) -78 deg C, 1.5 h

4: 84 percent / Amberlite IR 118

5: Et₃N / tetrahydrofuran

6: 76 percent / m-chloroperbenzoic acid, NaOAc / CH₂Cl₂ / 48 h / Ambient temperature

7: 95 percent / H₂ / 10percent Pd/C / petroleum ether

8: 95 percent / n-Bu₄N⁽¹⁺⁾F^(1-) / tetrahydrofuran

9: 72 percent / DMSO, Et₃N, trifluoroacetic acid / CH₂Cl₂ / -60 °C

With n-butyllithium; Amberlite IR 118; tetrabutyl ammonium fluoride; hydrogen; sodium acetate; dimethyl sulfoxide; triethylamine; 3-chloro-benzenecarboperoxoic acid; trifluoroacetic acid; zinc; palladium on activated charcoal; In tetrahydrofuran; dichloromethane; Petroleum ether;
DOI:10.1039/c39850000078