Methyl [2-(2-oxoethyl)-1,3-dioxolan-2-yl]acetate

Base Information

Chemical Name:Methyl [2-(2-oxoethyl)-1,3-dioxolan-2-yl]acetate
CAS No.:96725-02-9
Molecular Formula:C₈H₁₂O₅
Molecular Weight:188.18
Hs Code.:2932999099
DSSTox Substance ID:DTXSID80542150
Wikidata:Q82418717
Mol file:96725-02-9.mol

Synonyms:96725-02-9;Methyl [2-(2-oxoethyl)-1,3-dioxolan-2-yl]acetate;SCHEMBL9811332;DTXSID80542150;AKOS006310553

Suppliers and Price of Methyl [2-(2-oxoethyl)-1,3-dioxolan-2-yl]acetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
METHYL-2-(2-(FORMYLMETHYL)-1,3-DIOXOLAN-2-YL)ACETATE 95.00%
5MG
$ 499.02

Total 0 raw suppliers

Chemical Property of Methyl [2-(2-oxoethyl)-1,3-dioxolan-2-yl]acetate

Chemical Property:

PSA：61.83000
LogP:-0.11840
XLogP3:-1.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:5
Exact Mass:188.06847348
Heavy Atom Count:13
Complexity:195

Purity/Quality:: METHYL-2-(2-(FORMYLMETHYL)-1,3-DIOXOLAN-2-YL)ACETATE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)CC1(OCCO1)CC=O

Technology Process of Methyl [2-(2-oxoethyl)-1,3-dioxolan-2-yl]acetate

There total 4 articles about Methyl [2-(2-oxoethyl)-1,3-dioxolan-2-yl]acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 6506-31-6
dimethyl acetonedicarboxylate ethylene ketal

: 96725-02-9
methyl 3,3-(ethylenedioxy)-4-formylbutyrate

Guidance literature:: With diisobutylaluminium hydride; In dichloromethane; at -78 ℃; for 2h;
DOI:10.1016/S0040-4039(00)98490-9

Reference yield: 72.0%

: 5746-02-1
5-oxopentanoic acid

: 96725-02-9
methyl 3,3-(ethylenedioxy)-4-formylbutyrate

Guidance literature:

Reference yield:

: 1830-54-2
3-oxopentanedioic acid dimethyl ester

: 96725-02-9
methyl 3,3-(ethylenedioxy)-4-formylbutyrate

Guidance literature:: Multi-step reaction with 2 steps

1: 66 percent / pTsOH / tetrahydrofuran / 48 h / 70 °C

2: 82 percent / DIBAL / CH₂Cl₂ / 2 h / -78 °C

With diisobutylaluminium hydride; toluene-4-sulfonic acid; In tetrahydrofuran; dichloromethane;
DOI:10.1016/S0040-4039(00)98490-9