Benzene,1,1'-[(1R,2R,3R,4R)-3,4-dimethyl-1,- 2-cyclobutanediyl]bis[2,4,5-trimethoxy-,rel-

Base Information

• Chemical Name: Benzene,1,1'-[(1R,2R,3R,4R)-3,4-dimethyl-1,- 2-cyclobutanediyl]bis[2,4,5-trimethoxy-,rel-
• CAS No.: 81861-74-7
• Molecular Formula: C₂₄H₃₂O₆
• Molecular Weight: 416.514

Synonyms:

Chemical Property of Benzene,1,1'-[(1R,2R,3R,4R)-3,4-dimethyl-1,- 2-cyclobutanediyl]bis[2,4,5-trimethoxy-,rel-

Chemical Property:

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzene,1,1'-[(1R,2R,3R,4R)-3,4-dimethyl-1,- 2-cyclobutanediyl]bis[2,4,5-trimethoxy-,rel-

There total 2 articles about Benzene,1,1'-[(1R,2R,3R,4R)-3,4-dimethyl-1,- 2-cyclobutanediyl]bis[2,4,5-trimethoxy-,rel- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 2.3%

α-asarone (2883-98-9) → Heterotropan (70280-35-2) + andamanicin (70280-35-2,73036-51-8,81861-74-7,113349-60-3,130323-08-9) + magnoshinin (1072432-04-2) + C24H32O6 (70280-35-2,73036-51-8,81861-74-7,113349-60-3,130323-08-9)

Guidance literature:

With phenanthrene; In acetonitrile; for 110h; Ambient temperature; Irradiation;

DOI:10.1016/S0040-4039(00)96227-0

Reference yield: 2.3%

α-asarone (2883-98-9) → Heterotropan (70280-35-2) + andamanicin (70280-35-2,73036-51-8,81861-74-7,113349-60-3,130323-08-9) + magnoshinin (1072432-04-2) + C24H32O6 (70280-35-2,73036-51-8,81861-74-7,113349-60-3,130323-08-9)

Guidance literature:

With phenanthrene; In acetonitrile; for 110h; Ambient temperature; Irradiation;

DOI:10.1016/S0040-4039(00)96227-0

upstream raw materials:

α-asarone

Refernces

Synthesis of cyclobutane lignans via an organic single electron oxidant-electron relay system

10.1039/c3sc50643f

The study presents a method for synthesizing cyclobutane lignans and their analogs using photoinduced electron transfer. Key chemicals include oxygenated alkenes, which are used to form terminal or substituted cyclobutane adducts with complete regiocontrol and trans stereochemistry. The aromatic electron relay (ER), such as anthracene or naphthalene, is crucial for minimizing competing cycloreversion. The photooxidant 2,4,6-tris(4-methoxyphenyl)pyrylium tetrafluoroborate (p-OMeTPT) is used to excite the system and facilitate the oxidation of the alkene substrate by the ER, which then forms a cation radical capable of oxidizing the alkene. This method has been successfully applied to synthesize natural products like magnosalin and pellucidin A. The study also explores the role of the ER in preventing cycloreversion and polymerization, highlighting its importance in achieving higher yields and selectivity in the cyclobutane synthesis.

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 81861-74-7 Benzene,1,1'-[(1R,2R,3R,4R)-3,4-dimethyl-1,- 2-cyclobutanediyl]bis[2,4,5-trimethoxy-,rel-

Send

Send

Metric Ton KG G Pound L ML

Send

Send