Phosphorane, pentadecylidenetriphenyl-

Base Information

Chemical Name:Phosphorane, pentadecylidenetriphenyl-
CAS No.:97818-08-1
Molecular Formula:C33H45P
Molecular Weight:472.694
Hs Code.:
DSSTox Substance ID:DTXSID10454095
Wikidata:Q82275431

Synonyms:Phosphorane, pentadecylidenetriphenyl-;97818-08-1;DTXSID10454095

Suppliers and Price of Phosphorane, pentadecylidenetriphenyl-

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Phosphorane, pentadecylidenetriphenyl-

Chemical Property:

XLogP3:10.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:16
Exact Mass:472.32588843
Heavy Atom Count:34
Complexity:478

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CCCCCCCCCCCCCCC=P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3

Technology Process of Phosphorane, pentadecylidenetriphenyl-

There total 1 articles about Phosphorane, pentadecylidenetriphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 25791-20-2
(n-tetradecyl)triphenylphosphonium bromide

: 97818-08-1
Pentadecylidene-triphenyl-λ⁵-phosphane

Guidance literature:: With potassium hexamethylsilazane; In toluene; at 0 ℃; for 0.5h;
DOI:10.3762/bjoc.12.94

Reference yield: 85.0%

: 634586-95-1
L-2-[(benzyloxycarbonyl)amino]-4-(tert-butyldimethylsilyloxy)-butylaldehyde

: 97818-08-1
Pentadecylidene-triphenyl-λ⁵-phosphane

: 634586-98-4
{(Z)-(S)-1-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-heptadec-2-enyl}-carbamic acid benzyl ester

Guidance literature:: In tetrahydrofuran;
DOI:10.1002/anie.200454215

Reference yield:

: 97818-08-1
Pentadecylidene-triphenyl-λ⁵-phosphane

: 554-62-1
D-ribo-phytosphingosine

Guidance literature:: Multi-step reaction with 7 steps

1: 80 percent / tetrahydrofuran / -78 deg C, 2 h. then 22 deg C, 14 h.

2: 94 percent / 2N sulfuric acid / acetic acid; H₂O; tetrahydrofuran / 24 h / Ambient temperature

3: 87 percent / diethyl ether; pyridine / 0 deg C, 2 h. then 22 deg C, 24 h.

4: 77 percent / triphenylphosphine, diethylazodicarboxylate / tetrahydrofuran / 22 °C

5: N-methylmorpholine N-oxide hydrate, osmium tetroxide / H₂O; 2-methyl-propan-2-ol; acetone / 24 h / 22 °C

6: 79 percent / hydrazine hydrate / ethanol / 2 h / 60 °C

7: 85 percent / aq. KOH / methanol / 22 deg C, 12 h. then 60 deg C, 3 h.

With potassium hydroxide; osmium(VIII) oxide; sulfuric acid; hydrazine hydrate; 4-methylmorpholine N-oxide; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; pyridine; methanol; diethyl ether; ethanol; water; acetic acid; acetone; tert-butyl alcohol;
DOI:10.1016/S0040-4020(01)96078-8