Fullerene C70

Base Information

• Chemical Name: Fullerene C70
• CAS No.: 115383-22-7
• Molecular Formula: C₇₀
• Molecular Weight: 840.77
• Hs Code.: 28030000
• European Community (EC) Number: 634-223-5
• DSSTox Substance ID: DTXSID90151050
• Wikidata: Q3885009
• Wikipedia: C70_fullerene
• Mol file: 115383-22-7.mol

Synonyms:C70 fullerene;fullerene 70;fullerene C70

Chemical Property of Fullerene C70

Chemical Property:

• Appearance/Colour: black fine crystalline powder
• Melting Point: >280 °C (lit.)
• Boiling Point: 500-600℃ subl.
• PSA: 0.00000
• Density: 3.51 g/cm³
• LogP: 20.68500
• Storage Temp.: Dark Room
• Solubility.: benzene: soluble
• Water Solubility.: Soluble in benzene and toluene. Insoluble in water.
• XLogP3: 10.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 840
• Heavy Atom Count: 70
• Complexity: 4760

Purity/Quality:

98% ^*data from raw suppliers

[5,6]-Fullerene-c70 ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37-36/37/38
• Safety Statements: 26-36-24/25-22

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C12=C3C4=C5C6=C7C8=C9C%10=C%11C%12=C%13C%10=C%10C8=C5C1=C%10C1=C%13C5=C8C1=C2C1=C3C2=C3C%10=C%13C%14=C3C1=C8C1=C3C5=C%12C5=C8C%11=C%11C9=C7C7=C9C6=C4C2=C2C%10=C4C(=C29)C2=C6C(=C8C8=C9C6=C4C%13=C9C(=C%141)C3=C85)C%11=C27
• Uses: High-purity carbon 70 fullerenes for use in thermal evaporation systems, where increased optical absorption is important. Fullerene powder is used in chemical research. It is extensively used for several biomedical applications including the design of high-performance MRI contrast agents, X-Ray imaging contrast agents, photodynamic therapy and drug and gene delivery.
• Description: High-purity [5,6]-Fullerene-C70 (carbon 70 fullerenes, or C70) for use in thermal evaporation systems, where increased optical absorption is important.

Technology Process of Fullerene C70

There total 105 articles about Fullerene C70 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

bis[(ethoxycarbonyl)methyl] 1,2-methanol[70]fullerene-71,71-dicarboxylate → [5,6]fullerene-C70 (741268-81-5,741268-84-8,133227-82-4,133320-10-2,133320-11-3,133869-47-3,134054-62-9,134932-61-9,149820-05-3,149820-06-4,157903-26-9,175779-21-2,115383-22-7,958017-68-0,958017-71-5,958017-74-8,958017-77-1,958017-80-6,140630-87-1,140694-21-9,151716-50-6,157008-89-4,220062-79-3,220062-83-9)

Guidance literature:

With tert-butylammonium hexafluorophosphate(V); In dichloromethane; Electrolysis; 1E-6 Torr; 293 K, 30 min, -1.55 V (Pt-mesh (working electrode), Ag-wire (pseudoreference electrode)); chromy. (SiO2/toluene);

DOI:10.1002/(SICI)1521-3773(19980803)37:13/14<1919::AID-ANIE1919>3.0.CO;2-X

Reference yield: 64.0%

C74H9N3O2 → [5,6]fullerene-C70 (741268-81-5,741268-84-8,133227-82-4,133320-10-2,133320-11-3,133869-47-3,134054-62-9,134932-61-9,149820-05-3,149820-06-4,157903-26-9,175779-21-2,115383-22-7,958017-68-0,958017-71-5,958017-74-8,958017-77-1,958017-80-6,140630-87-1,140694-21-9,151716-50-6,157008-89-4,220062-79-3,220062-83-9) + C74H9NO2 + C74H9NO2

Guidance literature:

In toluene; at 80 ℃;

DOI:10.1021/ja963063j

Reference yield: 64.0%

C74H9N3O2 → [5,6]fullerene-C70 (741268-81-5,741268-84-8,133227-82-4,133320-10-2,133320-11-3,133869-47-3,134054-62-9,134932-61-9,149820-05-3,149820-06-4,157903-26-9,175779-21-2,115383-22-7,958017-68-0,958017-71-5,958017-74-8,958017-77-1,958017-80-6,140630-87-1,140694-21-9,151716-50-6,157008-89-4,220062-79-3,220062-83-9) + C74H9NO2 + C74H9NO2

Guidance literature:

In toluene; at 80 ℃;

DOI:10.1021/ja963063j

upstream raw materials:

1,9-(7171,72,72-tetraethoxycyclobutano)dihydro[70]fullerene

tetrathiafulvalenium radical cation

bis(ethylenedithio)tetrathiafulvalene cation radical

(+/-)-tetraethyl 1,2:56,57-bis(methano)<70>fullerene-71,71,72,72-tetracarboxylate

Refernces

An efficient route to the synthesis of symmetric and asymmetric diastereomerically pure fullerene triads

10.1016/j.tet.2012.04.061

The research presents a novel synthetic method for creating linear, diastereomerically pure fullerene triads, which are compounds consisting of two fullerene cages linked by an organic spacer. The purpose of this study is to develop a versatile and efficient route for synthesizing these triads, which have potential applications in molecular electronics, artificial photosynthetic systems, and supramolecular chemistry. The key chemicals used include fullerene C60 and C70, N,N'-dicyclohexylcarbodiimide (DCC) for activation, and various dicarboxylic acids and fulleropyrrolidines as precursors. The method involves functionalizing fullerene cages via a Prato reaction to form pyrrolidine rings, followed by a DCC-activated amidation reaction to link the fullerene cages. The study concludes that the yield of the coupling reaction is maximized in o-dichlorobenzene at high concentrations of the reactant fullerene nucleophile, while more polar solvents or lower concentrations favor the formation of unwanted side-products. The resultant triads exhibit good solubility in common organic solvents, enabling detailed characterization by NMR, IR, UV-vis spectroscopy, and MALDI-TOF mass spectrometry. This method allows for the flexible introduction of different fullerene cages and spacers, providing a wide range of symmetric and asymmetric fullerene structures without forming diastereomeric mixtures.