Gonyauline

Base Information

Chemical Name:Gonyauline
CAS No.:125559-51-5
Molecular Formula:C₆H₁₀O₂S
Molecular Weight:146.21
Hs Code.:
DSSTox Substance ID:DTXSID90154788
Wikidata:Q83022113
Metabolomics Workbench ID:170926
Mol file:125559-51-5.mol

Synonyms:gonyauline;S-methyl-cis-2-(methylthio)cyclopropanecarboxylic acid

Suppliers and Price of Gonyauline

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of Gonyauline

Chemical Property:

Boiling Point:°Cat760mmHg
Flash Point:°C
PSA：65.43000
Density:g/cm³
LogP:-0.99730
XLogP3:1.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:146.04015073
Heavy Atom Count:9
Complexity:128

Purity/Quality:: 98%min ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[S+](C)C1CC1C(=O)[O-]
Isomeric SMILES:C[S+](C)[C@@H]1C[C@@H]1C(=O)[O-]

Technology Process of Gonyauline

There total 10 articles about Gonyauline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.0%

: 132905-37-4,136288-44-3
Toluene-4-sulfonate((1R,2R)-1,2-dicarboxy-cyclopropyl)-dimethyl-sulfonium;

: 125559-51-5,125559-53-7,125559-58-2,132905-34-1,132905-35-2
(+/-)-Gonyauline

Guidance literature:: In tert-butyl alcohol; for 24h; Heating;
DOI:10.1039/P19900003219

Reference yield:

: 15619-30-4,58282-74-9,58282-75-0,132905-38-5
(1S,2S)-1-Methylsulfanyl-cyclopropane-1,2-dicarboxylic acid diethyl ester

: 125559-51-5
(+)-gonyauline

Guidance literature:: Multi-step reaction with 4 steps

1: OH^-, water

2: DCC, 4-pyrrolidinopyridine

3: 55 percent / LiOH / methanol; tetrahydrofuran

4: 2) acid / 2) decarboxylation in t-butyl alcohol

With lithium hydroxide; water; hydroxide; 4-pyrrolidin-1-ylpyridine; dicyclohexyl-carbodiimide; In tetrahydrofuran; methanol;
DOI:10.1016/S0040-4039(00)78868-X

Reference yield:

: 125559-52-6,125559-54-8,132905-39-6,132905-40-9
(1S,2S)-1-Methylsulfanyl-cyclopropane-1,2-dicarboxylic acid

: 125559-51-5
(+)-gonyauline

Guidance literature:: Multi-step reaction with 3 steps

1: DCC, 4-pyrrolidinopyridine

2: 55 percent / LiOH / methanol; tetrahydrofuran

3: 2) acid / 2) decarboxylation in t-butyl alcohol

With lithium hydroxide; 4-pyrrolidin-1-ylpyridine; dicyclohexyl-carbodiimide; In tetrahydrofuran; methanol;
DOI:10.1016/S0040-4039(00)78868-X