(R)-4-Hydroxy-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide

Base Information

Chemical Name:(R)-4-Hydroxy-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide
CAS No.:1193697-61-8
Molecular Formula:C20H21O4P
Molecular Weight:356.35
Hs Code.:
DSSTox Substance ID:DTXSID70432399
Nikkaji Number:J1.391.533D,J3.154.674E
Wikidata:Q72497179
Mol file:1193697-61-8.mol

Synonyms:1193697-61-8;(R)-4-Hydroxy-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide;297752-25-1;(11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin;(R)-4-Hydroxy-8,9,10,11,12,13,14,15-octahydro-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide;13-hydroxy-12,14-dioxa-13lambda5-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3(8),9,16,18(23)-hexaene 13-oxide;MFCD22200734;(S)-4-Hydroxy-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide;SCHEMBL6557292;DTXSID70432399;AKOS016004352;AS-74907;CS-0090907;CS-0092925;FT-0701504;FT-0701582;E77552;A892578;(11bS)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin;(R)-4-Hydroxy-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide;(S)-4-Hydroxy-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide;13-hydroxy-12,14-dioxa-13??-phosphapentacyclo[13.8.0.0(2),(1)(1).0(3),?.0(1)?,(2)(3)]tricosa-1(15),2,8,10,16,18(23)-hexaen-13-one;4-Hydroxy-8,9,10,11,12,13,14,15-octahydro-4H-4lambda~5~-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-one;4-Hydroxy-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin 4-oxide;8,9,10,11,12,13,14,15-Octahydro-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-one;8,9,10,11,12,13,14,15-Octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-ol 4-oxide;Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 8,9,10,11,12,13,14,15-octahydro-4-hydroxy-, 4-oxide, (11bS)-

Suppliers and Price of (R)-4-Hydroxy-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
(R)-4-Hydroxy-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1'',2''-f][1,3,2]dioxaphosphepine4-oxide
2.5mg
$ 45.00

Strem Chemicals
(11bS)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, (99% ee)
100mg
$ 183.00

Matrix Scientific
(R)-4-Hydroxy-8,9,10,11,12,13,14,15-octahydro-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide 95+%
500mg
$ 315.00

Matrix Scientific
(R)-4-Hydroxy-8,9,10,11,12,13,14,15-octahydro-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide 95+%
250mg
$ 205.00

Matrix Scientific
(R)-4-Hydroxy-8,9,10,11,12,13,14,15-octahydro-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide 95+%
1g
$ 485.00

Crysdot
(R)-4-Hydroxy-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 97%
1g
$ 483.00

Chemenu
(R)-4-Hydroxy-8,9,10,11,12,13,14,15-octahydro-dinaphtho[2,1-d:1'',2''-f][1,3,2]dioxaphosphepine4-oxide 97%
1g
$ 456.00

American Custom Chemicals Corporation
(R)-4-HYDROXY-8,9,10,11,12,13,14,15-OCTAHYDRODINAPHTHO-[2,1-D,1',2'-F][1,3,2]-DIOXAPHOSPHEPINE-4-OXIDE 95.00%
250MG
$ 426.30

Ambeed
(S)-4-Hydroxy-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%
250mg
$ 88.00

Ambeed
(S)-4-Hydroxy-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%
100mg
$ 48.00

Total 23 raw suppliers

Chemical Property of (R)-4-Hydroxy-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide

Chemical Property:

Boiling Point:579.7±60.0 °C(Predicted)
PKA:1.19±0.20(Predicted)
PSA：65.57000
Density:1.38
LogP:4.98280
Storage Temp.:Inert atmosphere,Room Temperature
XLogP3:5.1
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:0
Exact Mass:356.11774614
Heavy Atom Count:25
Complexity:508

Purity/Quality:

97% ^*data from raw suppliers

(R)-4-Hydroxy-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1'',2''-f][1,3,2]dioxaphosphepine4-oxide ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CCC2=C(C1)C=CC3=C2C4=C(C=CC5=C4CCCC5)OP(=O)(O3)O

Technology Process of (R)-4-Hydroxy-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide

There total 5 articles about (R)-4-Hydroxy-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 35193-63-6,35193-64-7,39648-67-4,50574-52-2
(S)-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate

: 1193697-61-8,297752-25-1
(S)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthalyl-2,2'-diylphosphoric acid

Guidance literature:: With platinum (IV) oxide; hydrogen; In methanol; dichloromethane; at 20 ℃; for 16h; under 760.051 Torr; chemoselective reaction; Sealed tube;
DOI:10.1021/acs.orglett.5b01754