6-O-Benzyl-2,3-di-O-acetyl-methyl-α-D-glucopyranoside

Base Information

• Chemical Name: 6-O-Benzyl-2,3-di-O-acetyl-methyl-α-D-glucopyranoside
• CAS No.: 162284-50-6
• Molecular Formula: C18H24O8
• Molecular Weight: 368.384
• Mol file: 162284-50-6.mol

Synonyms:6-O-Benzyl-2,3-di-O-acetyl-methyl-α-D-glucopyranoside;Methyl 6-O-(PhenylMethyl)-α-D-glucopyranoside 2,3-Diacetate

Chemical Property of 6-O-Benzyl-2,3-di-O-acetyl-methyl-α-D-glucopyranoside

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Boiling Point: 483.239°C at 760 mmHg
• Flash Point: 166.802°C
• PSA: 100.52000
• Density: 1.258g/cm³
• LogP: 0.79880
• Solubility.: Dichloromethane, Ethyl Acetate, Methanol

Purity/Quality:

97% ^*data from raw suppliers

6-O-Benzyl-2,3-di-O-acetyl-methyl-α-D-glucopyranoside ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 6-O-Benzyl-2,3-di-O-acetyl-methyl-α-D-glucopyranoside

There total 10 articles about 6-O-Benzyl-2,3-di-O-acetyl-methyl-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

methyl 2,3-di-O-acetyl-4,6-O-benzylidene-α-D-glucopyraniside (2774-22-3,4141-45-1,6748-84-1,6752-75-6,15451-81-7,20750-01-0,35311-30-9,56687-82-2,59121-47-0,72813-11-7,76333-82-9,112968-15-7,130464-34-5) → methyl 2,3-di-O-acetyl-6-O-benzyl-α-D-glucopyranoside (162284-50-6)

Guidance literature:

With triethylsilane; trifluoroacetic acid; In dichloromethane; Ambient temperature;

DOI:10.1016/0040-4039(94)02348-F

Reference yield: 93.0%

methyl 2,3-di-O-acetyl-4-O-(2,2-dimethyl-2-(ortho-nitrophenyl)acetyl)-6-O-benzyl-α-D-glucopyranoside → methyl 2,3-di-O-acetyl-6-O-benzyl-α-D-glucopyranoside (162284-50-6)

Guidance literature:

With copper(II) sulfate; acetic acid; zinc; In 1,4-dioxane; water; at 20 ℃; for 0.5h;

DOI:10.1021/acs.orglett.9b03025

Reference yield: 93.0%

→ methyl 2,3-di-O-acetyl-6-O-benzyl-α-D-glucopyranoside (162284-50-6)

Guidance literature:

With copper(II) sulfate; acetic acid; zinc; In 1,4-dioxane; water; at 20 ℃; for 0.5h;

upstream raw materials:

methyl 2,3-di-O-acetyl-4,6-O-benzylidene-α-D-glucopyraniside

methyl-4,6-O-benzylidene-2,3-diacetyl-α-D-glucopyranoside

benzaldehyde dimethyl acetal

methyl-alpha-D-glucopyranoside

Downstream raw materials:

methyl 2,3-di-O-acetyl-6-O-benzyl-4-O-levulinyl-α-D-glucopyranoside

methyl 2,3-di-O-acetyl-6-O-benzyl-4-iodo-α-D-galactopyranoside

methyl 4,5-di-O-acetyl-3-azido-6-O-(tert-butyldiphenylsilyl)-2-deoxy-α-D-galactopyranosyl-(1->4)-2,3-di-O-acetyl-6-O-benzyl-α-D-glucopyranoside

C₄₂H₅₀O₁₅