1-(Benzenesulfonyl)-2-phenylaziridine

Base Information

• Chemical Name: 1-(Benzenesulfonyl)-2-phenylaziridine
• CAS No.: 19871-46-6
• Molecular Formula: C14H13NO2S
• Molecular Weight: 259.329
• DSSTox Substance ID: DTXSID50941712
• Nikkaji Number: J645.065B,J3.424.091D
• Mol file: 19871-46-6.mol

Synonyms:DTXSID50941712;1-(benzenesulfonyl)-2-phenylaziridine;(1R,2R)-1-(Phenylsulfonyl)-2-phenylaziridine;19871-46-6

Chemical Property of 1-(Benzenesulfonyl)-2-phenylaziridine

Chemical Property:

• Vapor Pressure: 2.91E-07mmHg at 25°C
• Boiling Point: 420°Cat760mmHg
• Flash Point: 207.8°C
• Density: 1.324g/cm³
• XLogP3: 2.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 3
• Exact Mass: 259.06669983
• Heavy Atom Count: 18
• Complexity: 375

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1C(N1S(=O)(=O)C2=CC=CC=C2)C3=CC=CC=C3
• Isomeric SMILES: C1[C@H](N1S(=O)(=O)C2=CC=CC=C2)C3=CC=CC=C3

Technology Process of 1-(Benzenesulfonyl)-2-phenylaziridine

There total 14 articles about 1-(Benzenesulfonyl)-2-phenylaziridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

N-(2-chloro-2-phenylethyl)-N-fluorobenzenesulfonamide → 1-Benzenesulfonyl-2-phenyl-aziridine (19871-46-6)

Guidance literature:

With sodium hydroxide; In 1,2-dichloro-ethane; for 2h; Reflux;

DOI:10.1002/ejoc.201600709

Reference yield: 76.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + benzenesulfonamide (98-10-2) → 1-Benzenesulfonyl-2-phenyl-aziridine (19871-46-6)

Guidance literature:

With copper(II) hexafluoro-2,4-pentanedionate; [bis(acetoxy)iodo]benzene; In acetonitrile; at 25 ℃; for 12h;

DOI:10.1021/jo800134j

Reference yield: 73.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + chloramine-B (127-52-6) → 1-Benzenesulfonyl-2-phenyl-aziridine (19871-46-6)

Guidance literature:

With iodine; In acetonitrile; for 10h; Ambient temperature; neutral buffer, pH 6.86;

DOI:10.1016/S0040-4020(98)00827-8

upstream raw materials:

styrene

dibromamine-B

N,N-Dichlorobenzenesulfonamide

chloramine-B

Downstream raw materials:

9-<2-((phenylsulfonyl)amino)-1-phenylethyl>-9,10-dihydroanthracene

N-(3-Methanesulfinyl-1-phenyl-propyl)-benzenesulfonamide

1-Benzenesulfonyl-3,4-diphenyl-imidazolidin-2-one

1,1,2-triphenylethane