6,6'-Dicorynomycolyl trehalose

Base Information

• Chemical Name: 6,6'-Dicorynomycolyl trehalose
• CAS No.: 93379-98-7
• Molecular Formula: C₇₆H₁₄₆O₁₅
• Molecular Weight: 1299.99
• Mol file: 93379-98-7.mol

Synonyms:6,6'-dicorynomycolyl alpha, alpha'-trehalose;6,6'-dicorynomycolyl beta, beta'-trehalose;6,6'-dicorynomycolyl trehalose;DCYMT;S-TDCM;trehalose 6,6'-dicorynomycolate;trehalose dicorynomycolate

Chemical Property of 6,6'-Dicorynomycolyl trehalose

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Boiling Point: 1135.2°Cat760mmHg
• Flash Point: 272.5°C
• Density: 1.06g/cm³
• XLogP3: 24.9
• Hydrogen Bond Donor Count: 8
• Hydrogen Bond Acceptor Count: 15
• Rotatable Bond Count: 66
• Exact Mass: 1299.06617395
• Heavy Atom Count: 91
• Complexity: 1510

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CCCCCCCCCCCCCCCC(C(CCCCCCCCCCCCCC)C(=O)OCC1C(C(C(C(O1)OC2C(C(C(C(O2)COC(=O)C(CCCCCCCCCCCCCC)C(CCCCCCCCCCCCCCC)O)O)O)O)O)O)O)O
• Isomeric SMILES: CCCCCCCCCCCCCCCC(C(CCCCCCCCCCCCCC)C(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@@H](O1)OC2[C@@H]([C@H]([C@@H]([C@H](O2)COC(=O)C(CCCCCCCCCCCCCC)C(CCCCCCCCCCCCCCC)O)O)O)O)O)O)O)O

Technology Process of 6,6'-Dicorynomycolyl trehalose

There total 3 articles about 6,6'-Dicorynomycolyl trehalose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C106H222O15Si8 (138552-17-7) → 6,6'-di-O-<(2RS,3RS)-3-hydroxy-2-tetradecyloctadecanoyl>-α,α-trehalose (24863-90-9,59599-06-3,93379-98-7,93602-72-3,93714-04-6)

Guidance literature:

With tetrabutyl ammonium fluoride; potassium carbonate; trifluoroacetic acid; Yield given. Multistep reaction; 1) CHCl₃, RT, 3-4 h, 2) oxolane, RT, 1.5 h;

DOI:10.1016/0008-6215(91)84089-W

Reference yield:

C118H182O15 (74501-36-3,125177-99-3) → (2S,3R)-3-Hydroxy-2-tetradecyl-octadecanoic acid (2R,3S,4S,5R,6R)-3,4,5-trihydroxy-6-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-((2S,3R)-3-hydroxy-2-tetradecyl-octadecanoyloxymethyl)-tetrahydro-pyran-2-yloxy]-tetrahydro-pyran-2-ylmethyl ester (24863-90-9,59599-06-3,93379-98-7,93602-72-3,93714-04-6)

Guidance literature:

palladium on activated charcoal; Yield given;

DOI:10.1016/S0008-6215(00)85692-X

Reference yield:

→ 3-Hydroxy-2-tetradecyl-octadecanoic acid (2R,3S,4S,5R,6R)-3,4,5-trihydroxy-6-[(2S,3S,4R,5R,6S)-3,4,5-trihydroxy-6-(3-hydroxy-2-tetradecyl-octadecanoyloxymethyl)-tetrahydro-pyran-2-yloxy]-tetrahydro-pyran-2-ylmethyl ester (24863-90-9,59599-06-3,93379-98-7,93602-72-3,93714-04-6)

Guidance literature:

α,α-Trehalose, entspr. Fettsaeure;

DOI:10.1016/S0008-6215(00)84174-9

upstream raw materials:

C₁₀₆H₂₂₂O₁₅Si₈

C₁₁₈H₁₈₂O₁₅