Nitric acid trimethylsilyl ester

Base Information

• Chemical Name: Nitric acid trimethylsilyl ester
• CAS No.: 18026-82-9
• Molecular Formula: C3 H9 N O3 Si
• Molecular Weight: 135.195
• Mol file: 18026-82-9.mol

Synonyms:Silanol, trimethyl-, nitrate (6CI,8CI,9CI);Trimethylsilanol nitrate;Trimethylsilyl nitrate;

Chemical Property of Nitric acid trimethylsilyl ester

Chemical Property:

• Melting Point: -63.2 °C
• PSA: 55.05000
• LogP: 1.55280

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Nitric acid trimethylsilyl ester

There total 2 articles about Nitric acid trimethylsilyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

rac-2-ethyl-1-trimethylsilyoxy-hexane (18023-53-5) → Salpetersaeuretrimethylsilylester (18026-82-9) + 2-ethylhexanol nitrate (27247-96-7)

Guidance literature:

With dinitrogen pentoxide; In dichloromethane; at -5 - 8 ℃; for 1.5h;

DOI:10.1016/S0040-4020(97)00093-8

Reference yield: 13.0%

C10H26N2O2Si2 (87580-26-5) → methyl nitrate (598-58-3) + Salpetersaeuretrimethylsilylester (18026-82-9) + C7H17N3O4Si (135299-71-7)

Guidance literature:

With tin(IV) chloride; dinitrogen pentoxide; In dichloromethane; at -20 ℃; for 2h;

DOI:10.1007/BF00961361

upstream raw materials:

C₁₀H₂₆N₂O₂Si₂

rac-2-ethyl-1-trimethylsilyoxy-hexane

Refernces

• 1、 Kalinin, A. V.,Apasov, E. T.,Ioffe, S. L.,Tartakovskii, V. A.. "N-NITROHYDRAZINES AND THEIR SALTS". . p. 988 - 995. Retrieved 2007/10/02.