Methyl 3-amino-4-bromothiophene-2-carboxylate

Base Information

Chemical Name:Methyl 3-amino-4-bromothiophene-2-carboxylate
CAS No.:161833-42-7
Molecular Formula:C6H6BrNO2S
Molecular Weight:236.089
Hs Code.:2934999090
European Community (EC) Number:818-795-5
DSSTox Substance ID:DTXSID50693522
Wikidata:Q82622575
Mol file:161833-42-7.mol

Synonyms:methyl 3-amino-4-bromothiophene-2-carboxylate;161833-42-7;3-Amino-4-bromo-thiophene-2-carboxylic acid methyl ester;3-AMino-4-broMo-thiophene-2-carboxylicacidMethylester;MFCD09038329;SCHEMBL1845347;DTXSID50693522;LWSWLXPUUCBUPI-UHFFFAOYSA-N;AMY20672;BCP26743;AKOS015995128;DS-6435;SY023661;A3591;CS-0041706;methyl3-amino-4-bromothiophene-2-carboxylate;EN300-381106;H11841;J-511604;3-Amino-4-bromothiophene-2-carboxylic acid methyl ester;Z1269177426

Suppliers and Price of Methyl 3-amino-4-bromothiophene-2-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Methyl3-Amino-4-bromothiophene-2-carboxylate
50mg
$ 60.00

JR MediChem
2-Thiophenecarboxylicacid,3-amino-4-bromo-,methylester 96%
25g
$ 3980.00

JR MediChem
2-Thiophenecarboxylicacid,3-amino-4-bromo-,methylester 96%
5g
$ 1280.00

JR MediChem
2-Thiophenecarboxylicacid,3-amino-4-bromo-,methylester 96%
2g
$ 780.00

JR MediChem
2-Thiophenecarboxylicacid,3-amino-4-bromo-,methylester 96%
1g
$ 480.00

Crysdot
Methyl3-amino-4-bromothiophene-2-carboxylate 95+%
5g
$ 196.00

Crysdot
Methyl3-amino-4-bromothiophene-2-carboxylate 95+%
1g
$ 72.00

Chemenu
Methyl3-amino-4-bromothiophene-2-carboxylate 95%
25g
$ 771.00

Chemenu
Methyl3-amino-4-bromothiophene-2-carboxylate 95%
10g
$ 435.00

Chemenu
Methyl3-amino-4-bromothiophene-2-carboxylate 95%
5g
$ 229.00

Total 34 raw suppliers

Chemical Property of Methyl 3-amino-4-bromothiophene-2-carboxylate

Chemical Property:

Boiling Point:333.6±37.0 °C(Predicted)
PKA:-0.20±0.10(Predicted)
PSA：80.56000
Density:1.745±0.06 g/cm3(Predicted)
LogP:2.46060
Storage Temp.:2-8°C(protect from light)
XLogP3:2.4
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:2
Exact Mass:234.93026
Heavy Atom Count:11
Complexity:167

Purity/Quality:

97% ^*data from raw suppliers

Methyl3-Amino-4-bromothiophene-2-carboxylate ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C1=C(C(=CS1)Br)N

Technology Process of Methyl 3-amino-4-bromothiophene-2-carboxylate

There total 1 articles about Methyl 3-amino-4-bromothiophene-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 22288-78-4
Methyl 3-aminothiophene-2-carboxylate

: 161833-42-7
3-amino-4-bromo-2-thiophenecarboxylic acid methyl ester

Guidance literature:: With bromine; acetic acid; at 60 ℃; for 0.75h;

Reference yield: 97.0%

: 161833-42-7
3-amino-4-bromo-2-thiophenecarboxylic acid methyl ester

: 215927-34-7
3-amino-4-bromothiophene-2-carboxylic acid

Guidance literature:: With lithium hydroxide monohydrate; In methanol; water; at 80 ℃; for 4h;
DOI:10.1002/bkcs.10878

Reference yield: 86.0%

: 161833-42-7
3-amino-4-bromo-2-thiophenecarboxylic acid methyl ester

: 1765-93-1
4-fluoroboronic acid

: 156274-32-7
methyl 3-amino-4-(4-fluorophenyl)-2-thiophenecarboxylate

Guidance literature:: With palladium diacetate; sodium carbonate; triphenylphosphine; In 1,4-dioxane; water; at 80 ℃; for 2h;
DOI:10.1002/bkcs.10878