methyl 2,3-di-O-benzoyl-4-O-[(4-methylphenyl)sulfonyl]-6-O-tritylhexopyranoside

Base Information

Chemical Name:methyl 2,3-di-O-benzoyl-4-O-[(4-methylphenyl)sulfonyl]-6-O-tritylhexopyranoside
CAS No.:20231-37-2
Molecular Formula:C47H42O10S
Molecular Weight:798.8954
Hs Code.:
NSC Number:170240
DSSTox Substance ID:DTXSID20305327

Synonyms:NSC170240;20231-37-2;DTXSID20305327;NSC-170240

Suppliers and Price of methyl 2,3-di-O-benzoyl-4-O-[(4-methylphenyl)sulfonyl]-6-O-tritylhexopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of methyl 2,3-di-O-benzoyl-4-O-[(4-methylphenyl)sulfonyl]-6-O-tritylhexopyranoside

Chemical Property:

Vapor Pressure:1.23E-29mmHg at 25°C
Boiling Point:856°C at 760 mmHg
Flash Point:471.5°C
Density:1.34g/cm³
XLogP3:9.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:10
Rotatable Bond Count:16
Exact Mass:798.24986871
Heavy Atom Count:58
Complexity:1330

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC=C(C=C1)S(=O)(=O)OC2C(OC(C(C2OC(=O)C3=CC=CC=C3)OC(=O)C4=CC=CC=C4)OC)COC(C5=CC=CC=C5)(C6=CC=CC=C6)C7=CC=CC=C7

Technology Process of methyl 2,3-di-O-benzoyl-4-O-[(4-methylphenyl)sulfonyl]-6-O-tritylhexopyranoside

There total 1 articles about methyl 2,3-di-O-benzoyl-4-O-[(4-methylphenyl)sulfonyl]-6-O-tritylhexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 76-83-5
trityl chloride

: 4137-35-3,23397-67-3,102518-21-8,109681-62-1,117124-69-3,149035-49-4
methyl 2,3-di-O-benzoyl-α-D-glucopyranoside

: 20231-37-2
methyl 2,3-di-O-benzoyl-4-O-(p-tolylsulfonyl)-6-O-trityl-α-D-glucopyranoside

Guidance literature:: With pyridine; anschliessend Erwaermen mit Toluol-4-sulfonylchlorid;
DOI:10.1039/jr9530000992 DOI:10.1039/jr9580002511 DOI:10.1039/jr9350000685

Reference yield: 96.0%

: 20231-37-2
methyl 2,3-di-O-benzoyl-4-O-(p-tolylsulfonyl)-6-O-trityl-α-D-glucopyranoside

: 19488-44-9
methyl 2,3-di-O-benzoyl-4-O-(p-tolylsulfonyl)-α-D-glucopyranoside

Guidance literature:: With methanol; boron trifluoride; In dichloromethane; for 2h; Ambient temperature;
DOI:10.1016/S0040-4020(01)86679-5

Reference yield:

: 20231-37-2
methyl 2,3-di-O-benzoyl-4-O-(p-tolylsulfonyl)-6-O-trityl-α-D-glucopyranoside

: 6893-93-2
methyl 2,3-di-O-benzoyl-6-deoxy-4-O-(p-tolylsulfonyl)-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 96 percent / BF₃, CH₃OH / CH₂Cl₂ / 2 h / Ambient temperature

2: 84 percent / CBr₄, Ph₃P / acetonitrile / Ambient temperature

3: 89 percent / H₂ / Raney-Nickel / methanol; ethyl acetate

With methanol; carbon tetrabromide; boron trifluoride; hydrogen; triphenylphosphine; nickel; In methanol; dichloromethane; ethyl acetate; acetonitrile;
DOI:10.1016/S0040-4020(01)86679-5