(9,10-di(naphthalene-1-yl)anthracen-2-yl)boronic acid

Base Information

• Chemical Name: (9,10-di(naphthalene-1-yl)anthracen-2-yl)boronic acid
• CAS No.: 867044-35-7
• Molecular Formula: C34H23BO2
• Molecular Weight: 474.366
• Mol file: 867044-35-7.mol

Synonyms:Boronic acid, (9,10-di-1-naphthalenyl-2-anthracenyl)-

Chemical Property of (9,10-di(naphthalene-1-yl)anthracen-2-yl)boronic acid

Chemical Property:

• PSA: 40.46000
• LogP: 7.31320
• Storage Temp.: 2-8°C

Purity/Quality:

98%,99%, ^*data from raw suppliers

(9,10-Di(Naphthalen-1-yl)anthracen-2-yl)boronic acid 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (9,10-di(naphthalene-1-yl)anthracen-2-yl)boronic acid

There total 3 articles about (9,10-di(naphthalene-1-yl)anthracen-2-yl)boronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.2%

Triisopropyl borate (5419-55-6) + 2-bromo-9,10-bis(naphthalen-1-yl)anthracene (929031-39-0) + water (7732-18-5) → 9,10-di(1-naphthyl)-2-anthracenylboronic acid (867044-35-7)

Guidance literature:

2-bromo-9,10-bis(naphthalen-1-yl)anthracene; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 1.5h;

Triisopropyl borate; In tetrahydrofuran; at 20 ℃; for 24h;

water; With hydrogenchloride; In tetrahydrofuran;

Reference yield:

2-bromoanthracene-9,10-dione (572-83-8) → 9,10-di(1-naphthyl)-2-anthracenylboronic acid (867044-35-7)

Guidance literature:

Multi-step reaction with 3 steps

1.1: n-butyllithium / tetrahydrofuran / 1.5 h / -78 °C

1.2: 24 h / 20 °C

2.1: potassium iodide; sodium hypophosphite monohydrate; acetic acid / 3 h / Reflux

3.1: n-butyllithium / tetrahydrofuran / 1.5 h / -78 °C

3.2: 24 h / 20 °C

With n-butyllithium; sodium hypophosphite monohydrate; acetic acid; potassium iodide; In tetrahydrofuran;

Reference yield:

2-bromo-9,10-di-naphthalen-1-yl-9,10-dihydro-anthracene-9,10-diol (929031-38-9) → 9,10-di(1-naphthyl)-2-anthracenylboronic acid (867044-35-7)

Guidance literature:

Multi-step reaction with 2 steps

1.1: potassium iodide; sodium hypophosphite monohydrate; acetic acid / 3 h / Reflux

2.1: n-butyllithium / tetrahydrofuran / 1.5 h / -78 °C

2.2: 24 h / 20 °C

With n-butyllithium; sodium hypophosphite monohydrate; acetic acid; potassium iodide; In tetrahydrofuran;

upstream raw materials:

2-bromoanthracene-9,10-dione

Triisopropyl borate

2-bromo-9,10-bis(naphthalen-1-yl)anthracene

water

Refernces