N,N,N'-Triphenyl-4,4'-bianiline

Base Information

• Chemical Name: N,N,N'-Triphenyl-4,4'-bianiline
• CAS No.: 167218-30-6
• Molecular Formula: C30H24N2
• Molecular Weight: 412.534
• Hs Code.: 2921590090
• Mol file: 167218-30-6.mol

Synonyms:N,N,N'-Triphenyl-4,4'-bianiline;N,N,N'-Triphenyl-[1,1'-biphenyl]-4,4'-diamine;N-[4-(Diphenylamino)-1,1'-biphenyl-4'-yl]phenylamine;N4,N4,N4'-Triphenyl-[1,1'-biphenyl]-4,4'-diaMine

Chemical Property of N,N,N'-Triphenyl-4,4'-bianiline

Chemical Property:

• Melting Point: 168-169℃
• Boiling Point: 593.9±43.0 °C(Predicted)
• PKA: 0.90±0.40(Predicted)
• PSA: 15.27000
• Density: 1.172
• LogP: 8.64000
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature

Purity/Quality:

99% ^*data from raw suppliers

N,N,N'-Triphenylbenzidine >97.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N,N,N'-Triphenyl-4,4'-bianiline

There total 19 articles about N,N,N'-Triphenyl-4,4'-bianiline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.9%

(4-chlorobiphenyl-4'-yl)(N,N-diphenyl)amine (880800-25-9) + aniline (62-53-3) → N-(4'-anilino[1,1'-biphenyl]-4-yl)-N,N-diphenylamine (167218-30-6)

Guidance literature:

With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate; In toluene; at 125 ℃; for 10h;

Reference yield: 84.0%

aniline (62-53-3) + (4'-bromobiphenyl-4-yl)-diphenylamine (202831-65-0) → N-(4'-anilino[1,1'-biphenyl]-4-yl)-N,N-diphenylamine (167218-30-6)

Guidance literature:

With 1,1'-bis-(diphenylphosphino)ferrocene; sodium t-butanolate; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In toluene; at 100 ℃; for 6h;

DOI:10.1021/ma048365h

Reference yield: 81.0%

4-bromodiphenylamine (54446-36-5) + 4-(diphenylamino)phenyl boronic acid (201802-67-7) → N-(4'-anilino[1,1'-biphenyl]-4-yl)-N,N-diphenylamine (167218-30-6)

Guidance literature:

With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; In water; toluene; Inert atmosphere; Reflux;

upstream raw materials:

aniline

(4'-bromobiphenyl-4-yl)-diphenylamine

4-bromodiphenylamine

4-(diphenylamino)phenyl boronic acid

Downstream raw materials:

N,N'-bis[4'-(diphenylamino)biphenyl-4-yl]-N,N'-diphenyl-bis(4-aminophenyl)methylene

N,N'-bis[4'-(diphenylamino)biphenyl-4-yl]-N,N'-diphenyl-3,3'-dimethylbiphenyl-4,4'-diamine

N,N'-Bis[4'-(diphenylamino) biphenyl-4-yl]-N,N'-diphenyl-4,4'-diaminobiphenyl

C₉₁H₆₅N₅