Technology Process of ALPHA-ETHYLBENZYLAMINE
There total 65 articles about ALPHA-ETHYLBENZYLAMINE which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
2-Methyl-propane-2-sulfinic acid [1-phenyl-prop-(E)-ylidene]-amide;
With
[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; potassium tert-butylate; 2-Amino-2-methyl-1-propanol;
In
isopropyl alcohol;
at 50 ℃;
for 2h;
Molecular sieve;
With
hydrogenchloride;
In
methanol;
optical yield given as %ee;
diastereoselective reaction;
DOI:10.1016/j.tetlet.2010.12.031
- Guidance literature:
-
C13H19NOS;
With
[RhCl2(p-cymene)]2; potassium tert-butylate; (1S,2R)-1-amino-2-indanol;
In
isopropyl alcohol;
at 40 ℃;
for 4h;
Molecular sieve;
With
hydrogenchloride;
In
methanol;
optical yield given as %ee;
stereoselective reaction;
DOI:10.1016/j.tetlet.2009.07.044
- Guidance literature:
-
(1S,3S,4R)-2-benzyl-3-[(1S,4R)-7,7-dimethyl-2-oxobicyclo[2.2.1]hept-1-yl]-2-thioniabicyclo[2.2.1]heptane tetrafluoroborate;
With
lithium hexamethyldisilazane;
In
tetrahydrofuran; dichloromethane;
at -78 ℃;
for 1h;
triethyl borane;
In
tetrahydrofuran; dichloromethane;
at -100 - 0 ℃;
With
hydroxylamine-O-sulfonic acid;
In
tetrahydrofuran; dichloromethane;
at 0 - 20 ℃;
Further stages.;
DOI:10.1021/ja074110i
