Bis(phenylisoquinoline)(2,2,6,6-tetramethylheptane-3,5-dionate)iridium(III)

Base Information

• Chemical Name: Bis(phenylisoquinoline)(2,2,6,6-tetramethylheptane-3,5-dionate)iridium(III)
• CAS No.: 1202867-58-0
• Molecular Formula: C41H39IrN2O2
• Molecular Weight: 785.99300
• Mol file: 1202867-58-0.mol

Synonyms:Bis(phenylisoquinoline)(2,2,6,6-tetramethylheptane-3,5-dionate)iridium(III);Ir(dpm)(piq)2;Ir(dpM)(piq)2 , Bis(phenylisoquinoline)(2,2,6,6-tetraMethylhep

Chemical Property of Bis(phenylisoquinoline)(2,2,6,6-tetramethylheptane-3,5-dionate)iridium(III)

Chemical Property:

• PSA: 41.90000
• LogP: 8.31930

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Description: Ir(dpm)(piq)2, namely bis(phenylisoquinoline)(2,2,6,6-tetramethylheptane-3,5-dionate) iridium(III), is an iso-structure to Ir(dpm)PQ2. Ir(dpm)(piq)2?has one??2,2,6,6-tetramethylheptane-3,5-dionate?with two bulky?tert-butyl groups and two?phenylisoquinoline ligands coordinated to the iridium core.

Technology Process of Bis(phenylisoquinoline)(2,2,6,6-tetramethylheptane-3,5-dionate)iridium(III)

There total 2 articles about Bis(phenylisoquinoline)(2,2,6,6-tetramethylheptane-3,5-dionate)iridium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

bis[μ-chloro-bis(2-phenylisoquinolinato-C2,N)iridium(III)] + 2,2,6,6-tetramethyl-3-hydroxy-hept-3-en-5-one (55252-75-0) → bis(1-phenylisoquinolinato-N,C2’)iridium(2,2,6,6-tetramethyl-3,5-heptanedionate) (1202867-58-0)

Guidance literature:

With silver(l) oxide; In dichloromethane; for 2h; Sealed tube; Heating;

DOI:10.1002/anie.201709082

Reference yield: 88.0%

bis[μ-chloro-bis(2-phenylisoquinolinato-C2,N)iridium(III)] + 2,2,6,6-tetramethylheptane-3,5-dione (1118-71-4) → bis(1-phenylisoquinolinato-N,C2’)iridium(2,2,6,6-tetramethyl-3,5-heptanedionate) (1202867-58-0)

Guidance literature:

With potassium carbonate; In 2-ethoxy-ethanol; Reflux;

DOI:10.1016/j.crci.2015.06.016

upstream raw materials:

2,2,6,6-tetramethylheptane-3,5-dione

2,2,6,6-tetramethyl-3-hydroxy-hept-3-en-5-one