(2S,3R,4R)-3,4-Bis(benzyloxy)-2-(iodomethyl)-5-methoxytetrahydrofuran

Base Information

Chemical Name:(2S,3R,4R)-3,4-Bis(benzyloxy)-2-(iodomethyl)-5-methoxytetrahydrofuran
CAS No.:869476-25-5
Molecular Formula:C20H23IO4
Molecular Weight:454.305
Hs Code.:
DSSTox Substance ID:DTXSID20470685
Nikkaji Number:J3.507.231D
Mol file:869476-25-5.mol

Synonyms:869476-25-5;(2S,3R,4R)-3,4-Bis(benzyloxy)-2-(iodomethyl)-5-methoxytetrahydrofuran;(2S,3R,4R)-2-(iodomethyl)-5-methoxy-3,4-bis(phenylmethoxy)oxolane;MolPort-027-836-932;(2S,3R,4R)-3,4-BIS(BENZYLOXY)-2-(IODOMETHYL)-5-METHOXYOXOLANE;DTXSID20470685;A847923;(2S,3R,4R)-3,4-bis(benzyloxy)-2-(iodomethyl)-5-methoxy-tetrahydrofuran

Suppliers and Price of (2S,3R,4R)-3,4-Bis(benzyloxy)-2-(iodomethyl)-5-methoxytetrahydrofuran

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
(2S,3R,4R)-3,4-Bis(benzyloxy)-2-(iodomethyl)-5-methoxytetrahydrofuran 95+%
1g
$ 772.00

Chemenu
(2S,3R,4R)-3,4-bis(benzyloxy)-2-(iodomethyl)-5-methoxytetrahydrofuran 95%
1g
$ 729.00

American Custom Chemicals Corporation
(2S,3R,4R)-3,4-BIS(BENZYLOXY)-2-(IODOMETHYL)-5-METHOXYTETRAHYDROFURAN 95.00%
1G
$ 1575.00

American Custom Chemicals Corporation
(2S,3R,4R)-3,4-BIS(BENZYLOXY)-2-(IODOMETHYL)-5-METHOXYTETRAHYDROFURAN 95.00%
5MG
$ 496.50

Alichem
(2S,3R,4R)-3,4-Bis(benzyloxy)-2-(iodomethyl)-5-methoxytetrahydrofuran
1g
$ 640.56

Total 9 raw suppliers

Chemical Property of (2S,3R,4R)-3,4-Bis(benzyloxy)-2-(iodomethyl)-5-methoxytetrahydrofuran

Chemical Property:

PSA：36.92000
LogP:3.96350
Storage Temp.:2-8°C
XLogP3:3.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:8
Exact Mass:454.06411
Heavy Atom Count:25
Complexity:369

Purity/Quality:

97% ^*data from raw suppliers

(2S,3R,4R)-3,4-Bis(benzyloxy)-2-(iodomethyl)-5-methoxytetrahydrofuran 95+% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC1C(C(C(O1)CI)OCC2=CC=CC=C2)OCC3=CC=CC=C3
Isomeric SMILES:COC1[C@@H]([C@H]([C@H](O1)CI)OCC2=CC=CC=C2)OCC3=CC=CC=C3

Technology Process of (2S,3R,4R)-3,4-Bis(benzyloxy)-2-(iodomethyl)-5-methoxytetrahydrofuran

There total 8 articles about (2S,3R,4R)-3,4-Bis(benzyloxy)-2-(iodomethyl)-5-methoxytetrahydrofuran which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 220509-10-4
methyl 2,3-Di-O-benzyl-D-xylofuranoside

: 869476-25-5
methyl 2,3-di-O-benzyl-5-deoxy-5-iodo-D-xylofuranoside

Guidance literature:: With 1H-imidazole; iodine; triphenylphosphine; In tetrahydrofuran; Reflux;
DOI:10.1039/c5ob00532a

Reference yield: 90.0%

: 81927-55-1
O-benzyl 2,2,2-trichloroacetimidate

: 612051-06-6
methyl 5-deoxy-5-iodo-α/β-D-xyloside

: 869476-25-5
methyl 2,3-di-O-benzyl-5-deoxy-5-iodo-D-xylofuranoside

Guidance literature:: With trifluorormethanesulfonic acid; 4 A molecular sieve; In 1,4-dioxane; at 20 ℃; for 0.0833333h;
DOI:10.1021/jo051645q

Reference yield:

: 1824-96-0,1824-97-1,3795-68-4,3795-69-5,4229-54-3,5531-18-0,7473-45-2,13039-63-9,13039-64-0,13039-65-1,13039-67-3,22416-73-5,22861-09-2,25129-51-5,52485-92-4,52689-55-1,52689-56-2,56607-40-0,72880-70-7,79083-42-4,86782-30-1,86782-31-2,89615-03-2,89673-67-6,89707-99-3,102045-32-9,135910-17-7
methyl xylofuranoside

: 81927-55-1
O-benzyl 2,2,2-trichloroacetimidate

: 869476-25-5
methyl 2,3-di-O-benzyl-5-deoxy-5-iodo-D-xylofuranoside

Guidance literature:: methyl xylofuranoside; With pyridine; p-toluenesulfonyl chloride; at 20 ℃; for 48h;

O-benzyl 2,2,2-trichloroacetimidate; With trifluorormethanesulfonic acid; In 1,4-dioxane; at 20 ℃;

With sodium iodide; In 1,2-dimethoxyethane; at 90 ℃; for 48h;
DOI:10.1016/j.tetlet.2012.06.053