R-3,3'-Bis(phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate

Base Information

Chemical Name:R-3,3'-Bis(phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate
CAS No.:695162-86-8
Molecular Formula:C₃₂H₂₁O₄P
Molecular Weight:500.49
Hs Code.:
Mol file:695162-86-8.mol

Synonyms:SF110071;(R)-3,3'-Diphenyl-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate;R-3,3'-Bis(phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate;(R)-2,2'-Dihydroxy-3,3'-diphenyl-1,1'-binaphthalene cyclic phosphate;(R)-3,3'-Diphenyl-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate,99%e.e.;4-hydroxy-2,6-diphenyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide;(11bR)-4-Hydroxy-2,6-diphenyl-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin;(11bR)-4-Hydroxy-2,6-diphenyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide;Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 4-hydroxy-2,6-diphenyl-, 4-oxide, (11bR)-;(11BR)-4-HYDROXY-2,6-DIPHENYL-4-OXIDE-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN,98%,(99%EE)

Suppliers and Price of R-3,3'-Bis(phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Strem Chemicals
(11bR)-4-Hydroxy-2,6-diphenyl-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, (99% ee)
100mg
$ 123.00

Crysdot
(11bR)-4-Hydroxy-2,6-diphenyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 95+%
1g
$ 972.00

Ambeed
(11bR)-4-Hydroxy-2,6-diphenyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 97%
1g
$ 520.00

Ambeed
(11bR)-4-Hydroxy-2,6-diphenyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 97%
250mg
$ 138.00

Ambeed
(11bR)-4-Hydroxy-2,6-diphenyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 97%
100mg
$ 78.00

Alichem
(11bR)-4-Hydroxy-2,6-diphenyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide
1g
$ 1068.20

Total 12 raw suppliers

Chemical Property of R-3,3'-Bis(phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate

Chemical Property:

Melting Point:191.0-196.5 °C (decomp)(Solv: ethanol (64-17-5))
Boiling Point:755.1±70.0 °C(Predicted)
PKA:1.12±0.20(Predicted)
PSA：65.57000
Density:1.43±0.1 g/cm3(Predicted)
LogP:8.86560

Purity/Quality:

99% ^*data from raw suppliers

(11bR)-4-Hydroxy-2,6-diphenyl-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, (99% ee) ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of R-3,3'-Bis(phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate

There total 19 articles about R-3,3'-Bis(phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 861909-33-3,1644121-35-6
(R)-3,3'-dibromo-1,1'-binaphthalene-2,2'-diyl phosphoric acid

: 98-80-6
phenylboronic acid

: 874948-59-1,695162-86-8
(R_a)-4-hydroxy-2,6-diphenyldinaphtho[1,3,2]dioxaphosphepine 4-oxide

Guidance literature:: With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; potassium carbonate; In 1,2-dimethoxyethane; at 85 ℃; for 48h; Inert atmosphere;
DOI:10.1002/ejoc.201100328

Reference yield: 90.0%

: (R_a)-4-chloro-2,6-diphenyldinaphtho[1,3,2]dioxaphosphepine 4-oxide

: 874948-59-1,695162-86-8
(R_a)-4-hydroxy-2,6-diphenyldinaphtho[1,3,2]dioxaphosphepine 4-oxide

Guidance literature:: With pyridine; In water; at 100 ℃; Inert atmosphere;
DOI:10.1002/anie.201303527

Reference yield: 75.0%

: 75640-70-9,75684-93-4,102490-05-1,129301-81-1
(S)-3,3'-diphenyl-2,2'-dihydroxy-1,1'-binaphthyl

: 874948-59-1,695162-86-8
(S)-(-)-3,3’-bisphenyl-1,1’-bi-2-naphthyl phosphoric acid

Guidance literature:: (S)-3,3'-diphenyl-2,2'-dihydroxy-1,1'-binaphthyl; With pyridine; trichlorophosphate; for 5h; Inert atmosphere;

With water; In pyridine; for 0.5h;
DOI:10.1021/ol901114f