Boron, [m-[bis(1,1-dimethylethyl)[[(R)-(1,1-dimethylethyl)methylphosphino-kP]m ethyl]phosphine-kP]]hexahydrodi-

Base Information

Chemical Name:Boron, [m-[bis(1,1-dimethylethyl)[[(R)-(1,1-dimethylethyl)methylphosphino-kP]m ethyl]phosphine-kP]]hexahydrodi-
CAS No.:512184-96-2
Molecular Formula:C₁₄H₃₈B₂P₂
Molecular Weight:290.025
Hs Code.:2919900090
Mol file:512184-96-2.mol

Synonyms:(R)-(tert-Butylmethylphosphino-di-tert-butylphosphinomethane)diborane;Boron,[m-[bis(1,1-dimethylethyl)[[(R)-(1,1-dimethylethyl)methylphosphino-kP]methyl]phosphine-kP]]hexahydrodi-

Suppliers and Price of Boron, [m-[bis(1,1-dimethylethyl)[[(R)-(1,1-dimethylethyl)methylphosphino-kP]m ethyl]phosphine-kP]]hexahydrodi-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

SynQuest Laboratories
(R)-(tert-Butylmethylphosphino-di-tert-butylphosphinomethane)diborane
500 mg
$ 1472.00

Matrix Scientific
(R)-(tert-Butylmethylphosphino-di-tert-butylphosphinomethane)-diborane >95%
1g
$ 2678.00

Matrix Scientific
(R)-(tert-Butylmethylphosphino-di-tert-butylphosphinomethane)-diborane >95%
500mg
$ 1741.00

Total 1 raw suppliers

Chemical Property of Boron, [m-[bis(1,1-dimethylethyl)[[(R)-(1,1-dimethylethyl)methylphosphino-kP]m ethyl]phosphine-kP]]hexahydrodi-

Chemical Property:

Purity/Quality:

95% min. ^*data from raw suppliers

(R)-(tert-Butylmethylphosphino-di-tert-butylphosphinomethane)diborane ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Uses (R)-(tert-Butylmethylphosphino-di-tert-butylphosphinomethane)-diborane is used in the synthesis of P-?stereogenic bisphosphine ligands

Technology Process of Boron, [m-[bis(1,1-dimethylethyl)[[(R)-(1,1-dimethylethyl)methylphosphino-kP]m ethyl]phosphine-kP]]hexahydrodi-

There total 3 articles about Boron, [m-[bis(1,1-dimethylethyl)[[(R)-(1,1-dimethylethyl)methylphosphino-kP]m ethyl]phosphine-kP]]hexahydrodi- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 13716-10-4
di(tert-butyl)chlorophosphine

: 512184-96-2,512184-97-3,706819-97-8
tert-butylmethylphosphino-di-tert-butylphosphinomethane

Guidance literature:: tert-butyldimethylphosphine borane complex; With sec.-butyllithium; In tetrahydrofuran; at 0 - 20 ℃; for 1.3h;

di(tert-butyl)chlorophosphine; In tetrahydrofuran; at 0 - 20 ℃; for 2.3h;

With hydrogenchloride; dimethylsulfide borane complex; more than 3 stages;

Reference yield: 63.0%

: 13716-10-4
di(tert-butyl)chlorophosphine

: 203000-43-5
tert-butyldimethylphosphine borane complex

: 512184-96-2,512184-97-3,706819-97-8
tert-butylmethylphosphino-di-tert-butylphosphinomethane

Guidance literature:: tert-butyldimethylphosphine borane complex; With sec.-butyllithium; In tetrahydrofuran; at 0 ℃; for 1h;

di(tert-butyl)chlorophosphine; In tetrahydrofuran; at 0 ℃; for 2h;

With dimethylsulfide borane complex; In tetrahydrofuran; for 1h;
DOI:10.1021/ja048496y

Reference yield:

: 13716-10-4
di(tert-butyl)chlorophosphine

: 203000-43-5
tert-butyldimethylphosphine borane complex

: 512184-96-2,512184-97-3,706819-97-8
tert-butylmethylphosphino-di-tert-butylphosphinomethane

: (R)-t-butylmethylphosphino-di-t-butylphosphinomethane diborane

Guidance literature:: With dimethylsulfide borane complex; sec.-butyllithium; In tetrahydrofuran; treatment of Me3CP(Me)2BH3 with s-BuLi in THF at -78°C; addn. of di-tert-butylchlorophosphine; sepn. via chiral HPLC;
DOI:10.1021/ja048496y