Methyl 3-oxetane acetate

Base Information

• Chemical Name: Methyl 3-oxetane acetate
• CAS No.: 1217800-69-5
• Molecular Formula: C6H10O3
• Molecular Weight: 130.144
• Hs Code.: 2932999099
• Mol file: 1217800-69-5.mol

Synonyms:Methyl 3-oxetaneacetate;oxetan-3-yl-acetic acid methyl ester;METHYL OXETAN-3-YLACETATE;

Chemical Property of Methyl 3-oxetane acetate

Chemical Property:

• PSA: 35.53000
• LogP: 0.19590
• Storage Temp.: 2-8°C

Purity/Quality:

98%,99%, ^*data from raw suppliers

Methyl2-(Oxetan-3-yl)acetate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Methyl 3-oxetane acetate

There total 1 articles about Methyl 3-oxetane acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ methyl 2-(oxetan-3-yl)acetate (1217800-69-5)

Guidance literature:

Reference yield: 39.0%

methyl 2-(oxetan-3-yl)acetate (1217800-69-5) + (R)-N-((1E)-1-(5-bromo-2-fluorophenyl)ethylidene)-2-methylpropane-2-sulfinamide → methyl (2S,3S,4S)-2-(5-bromo-2-fluorophenyl)-1-((R)-tert-butylsulfinyl)-4-(hydroxymethyl)-2-methylpyrrolidine-3-carboxylate

Guidance literature:

methyl 2-(oxetan-3-yl)acetate; With lithium hexamethyldisilazane; In tetrahydrofuran; at -78 ℃;

With triisopropoxytitanium(IV) chloride; In tetrahydrofuran; hexane; at -78 ℃; for 0.5h;

(R)-N-((1E)-1-(5-bromo-2-fluorophenyl)ethylidene)-2-methylpropane-2-sulfinamide; In tetrahydrofuran; hexane; at -78 - 20 ℃;

DOI:10.1016/j.tet.2016.08.017

Reference yield: 30.0%

methyl 2-(oxetan-3-yl)acetate (1217800-69-5) + (RS)-2-methyl-N-(1-phenylethylidene)propane-2-sulfinamide (220263-59-2) → C18H27NO4S + C18H27NO4S

Guidance literature:

methyl 2-(oxetan-3-yl)acetate; With lithium hexamethyldisilazane; In tetrahydrofuran; at -78 ℃; for 0.25h;

With triisopropoxytitanium(IV) chloride; In tetrahydrofuran; hexane; at -78 ℃; for 0.5h;

(R_S)-2-methyl-N-(1-phenylethylidene)propane-2-sulfinamide; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 16h; diastereoselective reaction;

DOI:10.1016/j.tet.2016.08.017

Refernces