ethyl 2-(3,6-dihydro-2H-pyran-4-yl)-2-nitroacetate

Base Information

Chemical Name:ethyl 2-(3,6-dihydro-2H-pyran-4-yl)-2-nitroacetate
CAS No.:921755-40-0
Molecular Formula:C₉H₁₃NO₅
Molecular Weight:215.206
Hs Code.:
Mol file:921755-40-0.mol

Synonyms:ethyl 3,6-dihydro-2H-pyran-4-yl-nitroacetate;ethyl 2-(2-furylmethylidene)-3-oxobutanoate;ethyl 2-acetyl-3-(furan-2-yl)acrylate;ethyl 2-(2H,3H,5H-4-oxinyl)-2-nitroacetate;2-furfurylidene acetoacetic ester;ethyl (2Z)-2-(furan-2-ylmethylidene)-3-oxobutanoate;2-Furfurylidenacetessigester;ethyl 2-furfurylideneacetoacetate;Butanoic acid,2-(2-furanylmethylene)-3-oxo-,ethyl ester,(Z);Furfurylidenacetessigsaeure-ethylester;

Suppliers and Price of ethyl 2-(3,6-dihydro-2H-pyran-4-yl)-2-nitroacetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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ChemScene
Ethyl2-(3,6-dihydro-2H-pyran-4-yl)-2-nitroacetate
500mg
$ 715.00

Total 7 raw suppliers

Chemical Property of ethyl 2-(3,6-dihydro-2H-pyran-4-yl)-2-nitroacetate

Chemical Property:

PSA：81.35000
LogP:1.06470

Purity/Quality:

≥95% ^*data from raw suppliers

Ethyl2-(3,6-dihydro-2H-pyran-4-yl)-2-nitroacetate ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

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Technology Process of ethyl 2-(3,6-dihydro-2H-pyran-4-yl)-2-nitroacetate

There total 2 articles about ethyl 2-(3,6-dihydro-2H-pyran-4-yl)-2-nitroacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 29943-42-8,143562-54-3
Tetrahydro-4H-pyran-4-one

: 626-35-7
nitroacetic acid ethyl ester

: 921755-40-0
ethyl 3,6-dihydro-2H-pyran-4-yl-nitroacetate

Guidance literature:: nitroacetic acid ethyl ester; With titanium tetrachloride; In tetrahydrofuran; at 0 ℃; for 0.0833333h;

Tetrahydro-4H-pyran-4-one; With 4-methyl-morpholine; In tetrahydrofuran; at 0 - 20 ℃; for 20h;

Reference yield:

: 29943-42-8,143562-54-3
Tetrahydro-4H-pyran-4-one

: 626-35-7
nitroacetic acid ethyl ester

: 921755-40-0
ethyl 3,6-dihydro-2H-pyran-4-yl-nitroacetate

: ethyl nitrotetrahydropyran-4-ylideneacetate

Guidance literature:: nitroacetic acid ethyl ester; With titanium tetrachloride; In tetrahydrofuran; at 0 ℃; for 0.0833333h;

Tetrahydro-4H-pyran-4-one; With 4-methyl-morpholine; In tetrahydrofuran; at 20 ℃; for 18h; Title compound not separated from byproducts;
DOI:10.1021/jo061977a

Reference yield: 100.0%

: 921755-40-0
ethyl 3,6-dihydro-2H-pyran-4-yl-nitroacetate

: 646055-93-8
ethyl aminotetrahydropyran-4-ylacetate

Guidance literature:: ethyl 3,6-dihydro-2H-pyran-4-yl-nitroacetate; With hydrogenchloride; hydrogen; nickel; In ethanol; water; for 18h; under 2585.81 Torr; Parr hydrogenation apparatus;

In water; pH=8 - 9;