7-OXABICYCLO[4.1.0]HEPT-3-ENE-3-CARBOXYLIC ACID, 5-HYDROXY-, (1R,5S,6S)-

Base Information

Chemical Name:7-OXABICYCLO[4.1.0]HEPT-3-ENE-3-CARBOXYLIC ACID, 5-HYDROXY-, (1R,5S,6S)-
CAS No.:171596-14-8
Molecular Formula:C₇H₈O₄
Molecular Weight:156.138
Hs Code.:
DSSTox Substance ID:DTXSID00415716
Mol file:171596-14-8.mol

Synonyms:7-Oxabicyclo[4.1.0]hept-3-ene-3-carboxylicacid, 5-hydroxy-, [1R-(1a,5b,6a)]-; Doederleinic acid

Suppliers and Price of 7-OXABICYCLO[4.1.0]HEPT-3-ENE-3-CARBOXYLIC ACID, 5-HYDROXY-, (1R,5S,6S)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
(1R,5S,6S)-5-Hydroxy-7-oxabicyclo[4.1.0]hept-3-ene-3-carboxylicacid 95+%
1g
$ 1305.00

Chemenu
(1R,5S,6S)-5-hydroxy-7-oxabicyclo[4.1.0]hept-3-ene-3-carboxylicacid 95%
1g
$ 1230.00

American Custom Chemicals Corporation
DOEDERLEINIC ACID 95.00%
1G
$ 1953.00

American Custom Chemicals Corporation
DOEDERLEINIC ACID 95.00%
5MG
$ 495.70

Alichem
(1R,5S,6S)-5-Hydroxy-7-oxabicyclo[4.1.0]hept-3-ene-3-carboxylicacid
1g
$ 1108.80

Total 9 raw suppliers

Chemical Property of 7-OXABICYCLO[4.1.0]HEPT-3-ENE-3-CARBOXYLIC ACID, 5-HYDROXY-, (1R,5S,6S)-

Chemical Property:

Vapor Pressure:2.78E-08mmHg at 25°C
Boiling Point:405.9°C at 760 mmHg
Flash Point:179°C
PSA：70.06000
Density:1.613g/cm³
LogP:-0.47060
Storage Temp.:2-8°C
XLogP3:-0.7
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:1
Exact Mass:156.04225873
Heavy Atom Count:11
Complexity:233

Purity/Quality:

97% ^*data from raw suppliers

(1R,5S,6S)-5-Hydroxy-7-oxabicyclo[4.1.0]hept-3-ene-3-carboxylicacid 95+% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1C2C(O2)C(C=C1C(=O)O)O
Isomeric SMILES:C1[C@@H]2[C@@H](O2)[C@H](C=C1C(=O)O)O

Technology Process of 7-OXABICYCLO[4.1.0]HEPT-3-ENE-3-CARBOXYLIC ACID, 5-HYDROXY-, (1R,5S,6S)-

There total 6 articles about 7-OXABICYCLO[4.1.0]HEPT-3-ENE-3-CARBOXYLIC ACID, 5-HYDROXY-, (1R,5S,6S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 106861-60-3
(-)-methyl (1β,2β,6β)-2-hydroxy-7-oxabicyclo<4,1,0>hept-3-ene-4-carboxylate

: 213027-96-4,171596-14-8
(1R,5R,6S)-5-Hydroxy-7-oxa-bicyclo[4.1.0]hept-3-ene-3-carboxylic acid

Guidance literature:: With lithium hydroxide; In tetrahydrofuran; at 0 ℃; for 1h;
DOI:10.1021/ja992144n

Reference yield: 59.0%

: (1S,5S,6S)-5-Benzoyloxy-7-oxa-bicyclo[4.1.0]hept-3-ene-3-carboxylic acid methyl ester

: 213027-96-4,171596-14-8
(1S,5S,6R)-5-Hydroxy-7-oxa-bicyclo[4.1.0]hept-3-ene-3-carboxylic acid

Guidance literature:: With lithium hydroxide; In tetrahydrofuran; at 0 ℃; for 1h;
DOI:10.1021/ja992144n

Reference yield: 57.0%

: 76985-84-7
(-)-methyl (1β,2α,6β)-2-hydroxy-7-oxabicyclo<4,1,0>hept-3-ene-4-carboxylate

: 149560-23-6,206537-16-8,213027-96-4,171596-14-8
(1S,5R,6R)-5-hydroxy-7-oxa-bicyclo[4.1.0]hept-3-ene-3-carboxylic acid

Guidance literature:: (-)-methyl (1β,2α,6β)-2-hydroxy-7-oxabicyclo<4,1,0>hept-3-ene-4-carboxylate; With lithium hydroxide; water; In tetrahydrofuran; at -20 - 0 ℃; for 7h;

In tetrahydrofuran; pH=~ 5;