diquinoxalino[2,3-a:2',3'-c]phenazine

Base Information

• Chemical Name: diquinoxalino[2,3-a:2',3'-c]phenazine
• CAS No.: 214-83-5
• Molecular Formula: C24H12N6
• Molecular Weight: 384.39
• Mol file: 214-83-5.mol

Synonyms:Diquinoxalino[2,3-a:2',3'-c]phenazine; HATNA

Chemical Property of diquinoxalino[2,3-a:2',3'-c]phenazine

Chemical Property:

• Boiling Point: 738.6±25.0 °C(Predicted)
• PKA: -8.66±0.50(Predicted)
• PSA: 77.34000
• Density: 1.516±0.06 g/cm3(Predicted)
• LogP: 4.97580

Purity/Quality:

97% ^*data from raw suppliers

Diquinoxalino[2,3-a:2',3'-c]phenazine 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of diquinoxalino[2,3-a:2',3'-c]phenazine

There total 5 articles about diquinoxalino[2,3-a:2',3'-c]phenazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

hexaketocyclohexane (527-31-1) + 1,2-diamino-benzene (95-54-5) → diquinoxalino [2,3-a:2’,3’-c] phenazine (214-83-5)

Guidance literature:

hexaketocyclohexane; 1,2-diamino-benzene; With acetic acid; In ethanol; for 18h; Reflux;

With nitric acid; at 140 ℃; for 3h;

DOI:10.1039/d1ta06228j

Reference yield: 90.0%

2,3-diethynylquinoxaline (91-19-0) → diquinoxalino [2,3-a:2’,3’-c] phenazine (214-83-5)

Guidance literature:

With 2,2,6,6-tetramethyl-piperidine; n-butyllithium; In tetrahydrofuran; hexane; at -78 - 20 ℃; regioselective reaction; Inert atmosphere;

DOI:10.1002/jhet.4111

Reference yield:

3,4,9,10,15,16-hexamethyl-1,6,7,12,13,18-hexaazatrinaphthylene (23774-29-0) + 1,2-diamino-benzene (95-54-5) → diquinoxalino [2,3-a:2’,3’-c] phenazine (214-83-5)

Guidance literature:

With potassium hydroxide; In water; at 120 ℃; for 72h; Sealed tube; Inert atmosphere;

DOI:10.1016/j.chempr.2020.01.011

upstream raw materials:

hexaketocyclohexane

1,2-diamino-benzene

3,4,9,10,15,16-hexamethyl-1,6,7,12,13,18-hexaazatrinaphthylene

2,3-diethynylquinoxaline