Cyclobutane malonyl peroxide

Base Information

• Chemical Name: Cyclobutane malonyl peroxide
• CAS No.: 34867-87-3
• Molecular Formula: C6H6O4
• Molecular Weight: 142.111
• Mol file: 34867-87-3.mol

Synonyms:Cyclobutane malonyl peroxide

Chemical Property of Cyclobutane malonyl peroxide

Chemical Property:

• PSA: 52.60000
• LogP: 0.17170

Purity/Quality:

98%,99%, ^*data from raw suppliers

Cyclobutane malonyl peroxide ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T
• Statements: 25
• Safety Statements: 45

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Cyclobutane malonyl peroxide

There total 2 articles about Cyclobutane malonyl peroxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

cyclobutane-1,1'-dicarboxylic acid (5445-51-2) → spirocyclobutylmalonoyl peroxide (34867-87-3)

Guidance literature:

With methanesulfonic acid; urea hydrogen peroxide adduct; at 22 ℃; for 18h;

DOI:10.1021/ja1066674

Reference yield:

→ spirocyclobutylmalonoyl peroxide (34867-87-3)

Guidance literature:

Cyclobutan-1,1-dicarbonsaeure, H2O2;

DOI:10.1021/jo00959a045

Reference yield: 83.0%

spirocyclobutylmalonoyl peroxide (34867-87-3) + 1-phenyl-2-cyclopropylethylene (14799-60-1) → 1-(1-hydroxy-1-phenylmethyl)-1-hydroxymethylcyclopropane

Guidance literature:

spirocyclobutylmalonoyl peroxide; 1-phenyl-2-cyclopropylethylene; With water; In chloroform; at 40 ℃; for 18h;

With water; sodium hydroxide; In chloroform; at 40 ℃; for 18h;

DOI:10.1021/jo202084w

upstream raw materials:

cyclobutane-1,1'-dicarboxylic acid

Downstream raw materials:

phenylethane 1,2-diol

1-(p-chlorophenyl)-1,2-ethanediol

1-(4-methoxyphenyl) ethane-1,2-diol

Refernces

• 1、 Griffith, James C.,Jones, Kevin M.,Picon, Sylvain,Rawling, Michael J.,Kariuki, Benson M.,Campbell, Matthew,Tomkinson, Nicholas C. O.. "Alkene syn dihydroxylation with malonoyl peroxides". supporting information; experimental part. p. 14409 - 14411. Retrieved 2010/12/24.