1,4-Ethanoisoquinoline,9-ethoxy-1,2,3,4-tetrahydro-2-methyl-,(1alpha,4alpha,9R*)-(9CI)

Base Information

Chemical Name:1,4-Ethanoisoquinoline,9-ethoxy-1,2,3,4-tetrahydro-2-methyl-,(1alpha,4alpha,9R*)-(9CI)
CAS No.:109865-27-2
Molecular Formula:C₁₄H₁₉NO
Molecular Weight:217.311
Hs Code.:
Mol file:109865-27-2.mol

Synonyms:1,4-Ethanoisoquinoline,9-ethoxy-1,2,3,4-tetrahydro-2-methyl-,(1alpha,4alpha,9R*)-(9CI)

Suppliers and Price of 1,4-Ethanoisoquinoline,9-ethoxy-1,2,3,4-tetrahydro-2-methyl-,(1alpha,4alpha,9R*)-(9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1,4-Ethanoisoquinoline,9-ethoxy-1,2,3,4-tetrahydro-2-methyl-,(1alpha,4alpha,9R*)-(9CI)

Chemical Property:

PSA：12.47000
LogP:2.50340

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1,4-Ethanoisoquinoline,9-ethoxy-1,2,3,4-tetrahydro-2-methyl-,(1alpha,4alpha,9R*)-(9CI)

There total 3 articles about 1,4-Ethanoisoquinoline,9-ethoxy-1,2,3,4-tetrahydro-2-methyl-,(1alpha,4alpha,9R*)-(9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 109865-14-7
(1R,8R,11R)-11-Ethoxy-10-methoxy-9-aza-tricyclo[6.2.2.0^2,7]dodeca-2,4,6-triene-9-carboxylic acid ethyl ester

: 109865-27-2
(1R,8S,11S)-11-Ethoxy-9-methyl-9-aza-tricyclo[6.2.2.0^2,7]dodeca-2,4,6-triene

Guidance literature:: With LHA; In diethyl ether; for 5h; Heating;
DOI:10.1021/ja00252a015

Reference yield:

: 119-65-3
isoquinoline

: 109865-27-2
(1R,8S,11S)-11-Ethoxy-9-methyl-9-aza-tricyclo[6.2.2.0^2,7]dodeca-2,4,6-triene

Guidance literature:: Multi-step reaction with 3 steps

1: calcium carbonate / acetonitrile; methanol / 0.17 h / 0 °C

2: calcium carbonate / acetonitrile / 2 h / 0 °C

3: 78 percent / LHA / diethyl ether / 5 h / Heating

With calcium carbonate; In methanol; diethyl ether; acetonitrile;
DOI:10.1021/ja00252a015

Reference yield:

: 81357-89-3
2-(ethoxycarbonyl)isoquinolinium chloride

: 109865-27-2
(1R,8S,11S)-11-Ethoxy-9-methyl-9-aza-tricyclo[6.2.2.0^2,7]dodeca-2,4,6-triene

Guidance literature:: Multi-step reaction with 2 steps

1: calcium carbonate / acetonitrile / 2 h / 0 °C

2: 78 percent / LHA / diethyl ether / 5 h / Heating

With calcium carbonate; In diethyl ether; acetonitrile;
DOI:10.1021/ja00252a015