Methyl [(2,2,2-trichloroethoxy)sulfonyl]carbonochloridimidothioate

Base Information

Chemical Name:Methyl [(2,2,2-trichloroethoxy)sulfonyl]carbonochloridimidothioate
CAS No.:882739-48-2
Molecular Formula:C4H5Cl4NO3S2
Molecular Weight:321.033
Hs Code.:
European Community (EC) Number:693-927-0
Mol file:882739-48-2.mol

Synonyms:882739-48-2;Methyl [(2,2,2-trichloroethoxy)sulfonyl]carbonochloridimidothioate;2,2,2-trichloroethyl (NZ)-N-[chloro(methylsulfanyl)methylidene]sulfamate;S-Methyl N-(2,2,2-trichloroethoxysulfonyl)carbonchloroimidothioate;SCHEMBL21807888;DTXSID00584890;S-Methyl N-(2,2,2-trichloroethoxysulfonyl)carbonchloroimidothioate, 97%

Suppliers and Price of Methyl [(2,2,2-trichloroethoxy)sulfonyl]carbonochloridimidothioate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
S-Methyl N-(2,2,2-trichloroethoxysulfonyl)carbonchloroimidothioate 97%
5g
$ 474.00

Sigma-Aldrich
S-Methyl N-(2,2,2-trichloroethoxysulfonyl)carbonchloroimidothioate 97%
1g
$ 146.00

American Custom Chemicals Corporation
N-(2,2,2-TRICHLOROETHOXYSULFONYL)CARBONCHLOROTHIOIC ACID-S METHYL ESTER 95.00%
5MG
$ 499.43

Total 4 raw suppliers

Chemical Property of Methyl [(2,2,2-trichloroethoxy)sulfonyl]carbonochloridimidothioate

Chemical Property:

Melting Point:75-79 °C
PSA：89.41000
LogP:3.65660
XLogP3:3.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:4
Exact Mass:320.843546
Heavy Atom Count:14
Complexity:304

Purity/Quality:

99% ^*data from raw suppliers

S-Methyl N-(2,2,2-trichloroethoxysulfonyl)carbonchloroimidothioate 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xn
Statements: 22

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CSC(=NS(=O)(=O)OCC(Cl)(Cl)Cl)Cl
Isomeric SMILES:CS/C(=N/S(=O)(=O)OCC(Cl)(Cl)Cl)/Cl
Uses Reactant for preparation of:Muramycin analogs as antibacterial agents against drug-resistant bacteriaL-epicapreomycidine using rhodium-catalyzed stereoselective oxidative cyclization(+)-gonyautoxin 3 via Rh-catalyzed amination(+)-monobromophakellin and (+)-phakellin via a strategy applicable to synthesis of more complex members of this family of marine sponge-derived alkaloids including palau′amine2-imidazolidinones and 2-imino-1,3-imidazolidines

Technology Process of Methyl [(2,2,2-trichloroethoxy)sulfonyl]carbonochloridimidothioate

There total 2 articles about Methyl [(2,2,2-trichloroethoxy)sulfonyl]carbonochloridimidothioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: S,S-dimethyl-N-(2,2,2-trichloroethoxysulfonyl)carbonimidodithioate

: 882739-48-2
(2,2,2-trichloroethoxysulfonyl)carbonchloroimidothioic acid methyl ester

Guidance literature:: With sulfuryl dichloride; In dichloromethane; at 25 ℃; for 3h; Inert atmosphere;
DOI:10.1002/ejoc.201700263

Reference yield: 94.0%

: 882739-47-1
S-methyl-N-(2,2,2-trichloroethoxysulfonyl)isothiourea

: 882739-48-2
(2,2,2-trichloroethoxysulfonyl)carbonchloroimidothioic acid methyl ester

Guidance literature:: With sulfuryl dichloride; In dichloromethane; for 6h;
DOI:10.1021/ol052920y

Reference yield: 96.0%

: 882739-48-2
(2,2,2-trichloroethoxysulfonyl)carbonchloroimidothioic acid methyl ester

: 1061573-99-6
C₂₇H₃₃N₃O₂Si

: 1061574-16-0
C₂₈H₃₃Cl₃N₄O₅S₂Si

Guidance literature:: C₂₇H₃₃N₃O₂Si; With tetrakis(triphenylphosphine) palladium⁽⁰⁾; 1,3-dimethylbarbituric acid; In dichloromethane; for 8h; Inert atmosphere;

(2,2,2-trichloroethoxysulfonyl)carbonchloroimidothioic acid methyl ester; With sodium carbonate; In dichloromethane; water; for 0.333333h; Inert atmosphere;
DOI:10.1021/jacs.6b02343