2,4-Octadienoic acid, 7-(1-ethoxyethoxy)-6-methyl-, methyl ester

Base Information

Chemical Name:2,4-Octadienoic acid, 7-(1-ethoxyethoxy)-6-methyl-, methyl ester
CAS No.:86845-54-7
Molecular Formula:C₁₄H₂₄O₄
Molecular Weight:256.342
Hs Code.:
Mol file:86845-54-7.mol

Synonyms:2,4-Octadienoic acid, 7-(1-ethoxyethoxy)-6-methyl-, methyl ester

Suppliers and Price of 2,4-Octadienoic acid, 7-(1-ethoxyethoxy)-6-methyl-, methyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemicals and raw materials
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Total 3 raw suppliers

Chemical Property of 2,4-Octadienoic acid, 7-(1-ethoxyethoxy)-6-methyl-, methyl ester

Chemical Property:

PSA：44.76000
LogP:2.69550

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2,4-Octadienoic acid, 7-(1-ethoxyethoxy)-6-methyl-, methyl ester

There total 7 articles about 2,4-Octadienoic acid, 7-(1-ethoxyethoxy)-6-methyl-, methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 86845-53-6
(2E,4S,5R)-5-(1-Ethoxyethoxy)-4-methyl-2-hexen-1-al

: 21204-67-1,2605-67-6
methyl (triphenylphosphoranylidene)acetate

: 86845-54-7
(2E,4E,6S,7R)-7-(1-Ethoxyethoxy)-6-methyl-2,4-octadiensaeure-methylester

Guidance literature:: In toluene; at 90 ℃; for 25h;
DOI:10.1002/jlac.198319830607

Reference yield:

: 27372-03-8,51898-35-2,51898-36-3,63647-69-8,78088-27-4,78088-28-5,86853-34-1,92282-67-2,86853-33-0
ethyl anti-(2R,3R)-2-methyl-3-hydroxybutanoate

: 86845-54-7
(2E,4E,6S,7R)-7-(1-Ethoxyethoxy)-6-methyl-2,4-octadiensaeure-methylester

Guidance literature:: Multi-step reaction with 7 steps

1: 46.1 g / trifluoroacetic acid / 18 h / Ambient temperature

2: 1) LiAlH₄; 2) 15 percent KOH, / 2) Celite / 1) ether, 2.5 h at room temp.; 2) water, 30 min.

3: 76 percent / pyridine, chromtrioxide / CH₂Cl₂ / 0.5 h

4: 90 percent / toluene / 25 h / 90 °C

5: 80 percent / 20 percent diisobutyl aluminium hydride / toluene / 3 h / -70 - -6 °C

6: 89 percent / pyridine, chromtrioxide / CH₂Cl₂ / 0.5 h

7: 89 percent / toluene / 25 h / 90 °C

With pyridine; chromium(VI) oxide; potassium hydroxide; lithium aluminium tetrahydride; diisobutylaluminium hydride; Celite; In dichloromethane; toluene; trifluoroacetic acid;
DOI:10.1002/jlac.198319830607

Reference yield:

: 86845-49-0
(2R,3R)-3-(1-Ethoxyethoxy)-2-methylbuttersaeure-ethylester

: 86845-54-7
(2E,4E,6S,7R)-7-(1-Ethoxyethoxy)-6-methyl-2,4-octadiensaeure-methylester

Guidance literature:: Multi-step reaction with 6 steps

1: 1) LiAlH₄; 2) 15 percent KOH, / 2) Celite / 1) ether, 2.5 h at room temp.; 2) water, 30 min.

2: 76 percent / pyridine, chromtrioxide / CH₂Cl₂ / 0.5 h

3: 90 percent / toluene / 25 h / 90 °C

4: 80 percent / 20 percent diisobutyl aluminium hydride / toluene / 3 h / -70 - -6 °C

5: 89 percent / pyridine, chromtrioxide / CH₂Cl₂ / 0.5 h

6: 89 percent / toluene / 25 h / 90 °C

With pyridine; chromium(VI) oxide; potassium hydroxide; lithium aluminium tetrahydride; diisobutylaluminium hydride; Celite; In dichloromethane; toluene;
DOI:10.1002/jlac.198319830607