5,10,15,20-Tetrakis(2-nitrophenyl)-21,22-dihydroporphyrin

Base Information

Chemical Name:5,10,15,20-Tetrakis(2-nitrophenyl)-21,22-dihydroporphyrin
CAS No.:37116-82-8
Molecular Formula:C₄₄H₂₆N₈O₈
Molecular Weight:794.739
Hs Code.:
DSSTox Substance ID:DTXSID20452401
Mol file:37116-82-8.mol

Synonyms:37116-82-8;5,10,15,20-tetrakis(2-nitrophenyl)-21,22-dihydroporphyrin;DTXSID20452401

Suppliers and Price of 5,10,15,20-Tetrakis(2-nitrophenyl)-21,22-dihydroporphyrin

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
5,10,15,20-TETRA(2-NITROPHENYL)PORPHYRIN 95.00%
5MG
$ 501.88

Total 4 raw suppliers

Chemical Property of 5,10,15,20-Tetrakis(2-nitrophenyl)-21,22-dihydroporphyrin

Chemical Property:

PSA：239.58000
LogP:8.59180
XLogP3:9.7
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:10
Rotatable Bond Count:4
Exact Mass:794.18735982
Heavy Atom Count:60
Complexity:1480

Purity/Quality:

99% ^*data from raw suppliers

5,10,15,20-TETRA(2-NITROPHENYL)PORPHYRIN 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C(=C1)C2=C3C=CC(=C(C4=CC=C(N4)C(=C5C=CC(=N5)C(=C6C=CC2=N6)C7=CC=CC=C7[N+](=O)[O-])C8=CC=CC=C8[N+](=O)[O-])C9=CC=CC=C9[N+](=O)[O-])N3)[N+](=O)[O-]

Technology Process of 5,10,15,20-Tetrakis(2-nitrophenyl)-21,22-dihydroporphyrin

There total 7 articles about 5,10,15,20-Tetrakis(2-nitrophenyl)-21,22-dihydroporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

: 109-97-7,30604-81-0
pyrrole

: 552-89-6
2-nitro-benzaldehyde

: 37116-82-8,145032-18-4,145032-19-5
5,10,15,20-tetrakis(o-nitrophenyl)porphyrin

Guidance literature:: With air; propionic acid; for 0.0666667h; microwave irradiation;
DOI:10.1081/SCC-100000176

Reference yield:

: 5,10,15,20-Tetrakis-(2-nitro-phenyl)-porphyrinogene

: 37116-82-8,145032-18-4,145032-19-5
5,10,15,20-tetrakis(o-nitrophenyl)porphyrin

Guidance literature:: With chloranil; In chloroform; at 61 ℃; for 1h; Yield given;
DOI:10.1021/jo00265a021

Reference yield:

: 552-89-6
2-nitro-benzaldehyde

: 37116-82-8,145032-18-4,145032-19-5
5,10,15,20-tetrakis(o-nitrophenyl)porphyrin

Guidance literature:: Multi-step reaction with 2 steps

1: CF₃SO₂Cl / CH₂Cl₂ / 1 h / 20 °C

2: air / CH₂Cl₂ / 4 h / 39 °C

With air; trifluoromethane sulfonyl chloride; In dichloromethane;
DOI:10.1016/j.tet.2003.12.030