4-(hydroxyMethyl)-2-oxohexahydro-2H-cyclopenta[b]furan-5-yl benzoate

Base Information

Chemical Name:4-(hydroxyMethyl)-2-oxohexahydro-2H-cyclopenta[b]furan-5-yl benzoate
CAS No.:172821-93-1
Molecular Formula:C₁₅H₁₆O₅
Molecular Weight:276.289
Hs Code.:
Mol file:172821-93-1.mol

Synonyms:4-(hydroxyMethyl)-2-oxohexahydro-2H-cyclopenta[b]furan-5-yl benzoate

Suppliers and Price of 4-(hydroxyMethyl)-2-oxohexahydro-2H-cyclopenta[b]furan-5-yl benzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

ChemScene
4-(hydroxymethyl)-2-oxohexahydro-2H-cyclopenta[b]furan-5-ylbenzoate
500mg
$ 450.00

ChemScene
4-(hydroxymethyl)-2-oxohexahydro-2H-cyclopenta[b]furan-5-ylbenzoate
100mg
$ 150.00

Total 5 raw suppliers

Chemical Property of 4-(hydroxyMethyl)-2-oxohexahydro-2H-cyclopenta[b]furan-5-yl benzoate

Chemical Property:

PSA：72.83000
LogP:1.15590

Purity/Quality:

≥95% ^*data from raw suppliers

4-(hydroxymethyl)-2-oxohexahydro-2H-cyclopenta[b]furan-5-ylbenzoate ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 4-(hydroxyMethyl)-2-oxohexahydro-2H-cyclopenta[b]furan-5-yl benzoate

There total 22 articles about 4-(hydroxyMethyl)-2-oxohexahydro-2H-cyclopenta[b]furan-5-yl benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: Benzoic acid (3aR,4S,5R,6aS)-2-oxo-4-triethylsilanyloxymethyl-hexahydro-cyclopenta[b]furan-5-yl ester

: 39746-00-4,172821-93-1
(1S,5R,6S,7R)-7-benzoyloxy-6-hydroxymethyl-2-oxabicyclo[3.3.0]octan-3-one

Guidance literature:: With hydrogen; palladium on activated charcoal; In dichloromethane; at 20 ℃; for 0.0333333h; atmospheric pressure;
DOI:10.1016/j.tetlet.2003.12.145

Reference yield: 99.0%

: (1S,5R,6S,7R)-6-tert-Butyldimethylsilyloxymethyl-7-benzoyloxy-2-oxabicyclo[3.3.0]octan-3-one

: 39746-00-4,172821-93-1
(1S,5R,6S,7R)-7-benzoyloxy-6-hydroxymethyl-2-oxabicyclo[3.3.0]octan-3-one

Guidance literature:: With hydrogen; palladium on activated charcoal; In dichloromethane; at 20 ℃; for 4h; atmospheric pressure;
DOI:10.1016/j.tetlet.2003.12.145

Reference yield: 76.0%

: (3aR,5R,6aS)-4-methylene-2-oxohexahydro-2H-cyclopenta[b]furan-5-yl benzoate

: 172821-93-1
(3aR,4R,5R,6aS)-4-(hydroxymethyl)-2-oxohexahydro-2H-cyclopenta[b]furan-5-yl benzoate

Guidance literature:: (3aR,5R,6aS)-4-methylene-2-oxohexahydro-2H-cyclopenta[b]furan-5-yl benzoate; With dimethylsulfide borane complex; In tetrahydrofuran; at -30 - 0 ℃; for 12h; Inert atmosphere;

With dihydrogen peroxide; potassium carbonate; In tetrahydrofuran; water; at 20 ℃; for 8h; stereoselective reaction;
DOI:10.1039/c8ob00489g