Sn(IV) meso-Tetra (4-Pyridyl) Porphine Dichloride

Base Information

• Chemical Name: Sn(IV) meso-Tetra (4-Pyridyl) Porphine Dichloride
• CAS No.: 87261-83-4
• Molecular Formula: C₄₀H₂₄Cl₂N₈Sn
• Molecular Weight: 806.3
• Mol file: 87261-83-4.mol

Synonyms:Sn(IV) meso-Tetra (4-Pyridyl) Porphine Dichloride

Chemical Property of Sn(IV) meso-Tetra (4-Pyridyl) Porphine Dichloride

Chemical Property:

• PSA: 102.06000
• LogP: -2.66840

Purity/Quality:

99% ^*data from raw suppliers

Sn(IV)meso-Tetra(4-Pyridyl)PorphineDichloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Sn(IV) meso-Tetra (4-Pyridyl) Porphine Dichloride is a synthetic porphyrin for research.

Technology Process of Sn(IV) meso-Tetra (4-Pyridyl) Porphine Dichloride

There total 4 articles about Sn(IV) meso-Tetra (4-Pyridyl) Porphine Dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

5,10,15,20-tetra(4-pyridyl)-21H,23H-porphine (16834-13-2) → dichloro-(5,10,15,20-tetrakis-(4-pyridyl)-porphyrinato)tin(IV) (87261-83-4)

Guidance literature:

With tin(ll) chloride; In ethanol; chloroform; for 40h; Reflux;

DOI:10.1142/S1088424610002124

Reference yield:

pyridine-4-carbaldehyde (872-85-5) → dichloro-(5,10,15,20-tetrakis-(4-pyridyl)-porphyrinato)tin(IV) (87261-83-4)

Guidance literature:

Multi-step reaction with 2 steps

1: acetic anhydride / 1.5 h / 120 °C

2: pyridine / Reflux

With pyridine; In acetic anhydride;

DOI:10.1021/ic401611v

Reference yield:

tetra(4-pyridyl)porphyrine + tin(II) chloride dihdyrate (10025-69-1) → dichloro-(5,10,15,20-tetrakis-(4-pyridyl)-porphyrinato)tin(IV) (87261-83-4)

Guidance literature:

With pyridine; Reflux;

DOI:10.1021/ic401611v

upstream raw materials:

Sn-tetra(4-pyridyl)porphyrin^(1-) radical

5,10,15,20-tetra(4-pyridyl)-21H,23H-porphine

tin(II) chloride dihdyrate

pyridine-4-carbaldehyde

Refernces

• 1、 Shetti, Vijayendra S.,Ravikanth, Mangalampalli. "A simple alternative method for preparing Sn(IV) porphyrins". experimental part. p. 361 - 370. Retrieved 2010/11/21.