5,5′-Bis(mercaptomethyl)-2,2′-bipyridine

Base Information

• Chemical Name: 5,5′-Bis(mercaptomethyl)-2,2′-bipyridine
• CAS No.: 894105-98-7
• Molecular Formula: C12H12N2S2
• Molecular Weight: 248.37
• Mol file: 894105-98-7.mol

Synonyms:5,5′-Bis(mercaptomethyl)-2,2′-bipyridine ;5,5'-Bis(mercaptomethyl)-2,2'-bipyridine 96%

Chemical Property of 5,5′-Bis(mercaptomethyl)-2,2′-bipyridine

Chemical Property:

• Melting Point: 136-140°C
• PSA: 103.38000
• LogP: 3.00320

Purity/Quality:

98%,99%, ^*data from raw suppliers

5,5′-Bis(mercaptomethyl)-2,2′-bipyridine 96% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Useful:

• Uses: BPD can be used as a SAM that forms a sulfur functionalized layer on the gold surface for the formation of biocompatible interfaces for the immobilization of cells and proteins. It can prepare organic-metal-organic heterostructures using silver atoms which can be coated on the gold substrate for applications which include molecular electronics and plasmonics.

Technology Process of 5,5′-Bis(mercaptomethyl)-2,2′-bipyridine

There total 2 articles about 5,5′-Bis(mercaptomethyl)-2,2′-bipyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

5,5'-bis(bromomethyl)-2,2'-bipyridine (92642-09-6) → 5,5′-bis(mercaptomethyl)-2,2′-bipyridine (894105-98-7)

Guidance literature:

With thiourea; In 1,4-dioxane; for 3h; pH=Ca.4; Reflux; Inert atmosphere;

DOI:10.1002/ange.202007840

Reference yield:

2-(5'-carbamimidoylsulfanylmethyl-[2,2']bipyridinyl-5-ylmethyl)-isothiourea; compound with GENERIC INORGANIC NEUTRAL COMPONENT → 5,5′-bis(mercaptomethyl)-2,2′-bipyridine (894105-98-7)

Guidance literature:

With sodium hydroxide; In water; at 70 ℃; for 1h;

DOI:10.1021/ma049560z

Reference yield:

Carboxymethyl dithiobenzoate (942-91-6) + 5,5′-bis(mercaptomethyl)-2,2′-bipyridine (894105-98-7) → 5,5'-bis[(thiobenzoyl)thiomethyl]-2,2'-bipyridyne (773072-70-1)

Guidance literature:

In water; at 20 ℃; for 21h;

DOI:10.1021/ma049560z

upstream raw materials:

5,5'-bis(bromomethyl)-2,2'-bipyridine

Downstream raw materials:

5,5'-bis[(thiobenzoyl)thiomethyl]-2,2'-bipyridyne