N-Benzylidene-2-butanamine

Base Information

• Chemical Name: N-Benzylidene-2-butanamine
• CAS No.: 40051-50-1
• Molecular Formula: C11H15N
• Molecular Weight: 161.247
• Mol file: 40051-50-1.mol

Synonyms:N-Benzylidene-2-butanamine

Chemical Property of N-Benzylidene-2-butanamine

Chemical Property:

• Boiling Point: 86-88 °C(Press: 3 Torr)
• PKA: 5.87±0.50(Predicted)
• PSA: 12.36000
• Density: 0.9189 g/cm3
• LogP: 2.90400

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N-Benzylidene-2-butanamine

There total 10 articles about N-Benzylidene-2-butanamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

SEC-BUTYLAMINE (33966-50-6) + benzyl alcohol (100-51-6,185532-71-2) → N-benzylidene-sec-butylamine (40051-50-1)

Guidance literature:

With [H(3,5-trifluoromethylphenyl)4B]*2Et₂O; C₃₂H₆₃CoNP₂Si; In toluene; at 120 ℃; for 52h; Glovebox; Inert atmosphere;

DOI:10.1021/ol303479f

Reference yield: 75.0%

SEC-BUTYLAMINE (33966-50-6) + 3-chloro-3-phenyl-3H-diazirine (4460-46-2) → N-benzylidene-sec-butylamine (40051-50-1)

Guidance literature:

In hexane; at 25 ℃; for 7h; Irradiation;

DOI:10.1139/v94-250

Reference yield: 40.0%

nitrostyrene (5153-67-3) + SEC-BUTYLAMINE (33966-50-6) → N-benzylidene-sec-butylamine (40051-50-1)

Guidance literature:

With water; at 20 ℃; for 4h;

DOI:10.1016/j.tetlet.2007.12.042

upstream raw materials:

SEC-BUTYLAMINE

benzaldehyde

N-chlorobenzyl-sec-butylamine

3-chloro-3-phenyl-3H-diazirine

Downstream raw materials:

sec-Butyl-[2,2-dichloro-1-phenyl-eth-(E)-ylidene]-amine

Refernces

• 1、 Yu, Han,Wang, Jingjing,Zhai, Yongyan,Zhang, Mengqi,Ru, Shi,Han, Sheng,Wei, Yongge. "Visible-Light-Driven Photocatalytic Oxidation of Organic Chlorides Using Air and an Inorganic-Ligand Supported Nickel-Catalyst Without Photosensitizers". . p. 4274 - 4279. Retrieved 2018/09/10.
• 2、 Zhang, Guoqi,Hanson, Susan K.. "Cobalt-catalyzed acceptorless alcohol dehydrogenation: Synthesis of imines from alcohols and amines". supporting information. p. 650 - 653. Retrieved 2013/04/11.