Ethanone, 1-(8-azabicyclo[3.2.1]oct-2-en-2-yl)-, (1S)- (9CI)

Base Information

Chemical Name:Ethanone, 1-(8-azabicyclo[3.2.1]oct-2-en-2-yl)-, (1S)- (9CI)
CAS No.:172277-65-5
Molecular Formula:C₉H₁₃NO
Molecular Weight:151.208
Hs Code.:
Mol file:172277-65-5.mol

Synonyms:Ethanone, 1-(8-azabicyclo[3.2.1]oct-2-en-2-yl)-, (1S)- (9CI)

Suppliers and Price of Ethanone, 1-(8-azabicyclo[3.2.1]oct-2-en-2-yl)-, (1S)- (9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of Ethanone, 1-(8-azabicyclo[3.2.1]oct-2-en-2-yl)-, (1S)- (9CI)

Chemical Property:

PSA：29.10000
LogP:1.35490

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Ethanone, 1-(8-azabicyclo[3.2.1]oct-2-en-2-yl)-, (1S)- (9CI)

There total 19 articles about Ethanone, 1-(8-azabicyclo[3.2.1]oct-2-en-2-yl)-, (1S)- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 172172-48-4
(1R,5S)-4-acetyl-8-tert-butoxycarbonyl-8-azabicyclo[3.2.1]oct-3-ene

: 172277-65-5
(+)-norferruginine

Guidance literature:: With trifluoroacetic acid; In dichloromethane; for 3h; Ambient temperature;
DOI:10.1021/jo9515081

Reference yield:

: 691383-50-3
tert-butyl (2R,5S)-2-allyl-5-ethynyl-1-pyrrolidinecarboxylate

: 172277-65-5
(+)-norferruginine

Guidance literature:: Multi-step reaction with 3 steps

1: bis(tricyclohexylphosphine)benzylidene ruthenium dichloride / CH₂Cl₂ / 10 h / Heating

2: 81 percent / CuCl₂; PdCl₂; air / dimethylformamide; H₂O / 6 h / Heating

3: 93 percent / CF₃CO₂H / CH₂Cl₂ / 3 h / 25 °C

With air; trifluoroacetic acid; copper dichloride; palladium dichloride; Grubbs catalyst first generation; In dichloromethane; water; N,N-dimethyl-formamide; 2: Wacker oxidation;
DOI:10.1021/ol049665m

Reference yield:

: 691383-54-7
tert-butyl (1S,5R)-2-vinyl-8-azabicyclo[3.2.1]oct-2-ene-8-carboxylate

: 172277-65-5
(+)-norferruginine

Guidance literature:: Multi-step reaction with 2 steps

1: 81 percent / CuCl₂; PdCl₂; air / dimethylformamide; H₂O / 6 h / Heating

2: 93 percent / CF₃CO₂H / CH₂Cl₂ / 3 h / 25 °C

With air; trifluoroacetic acid; copper dichloride; palladium dichloride; In dichloromethane; water; N,N-dimethyl-formamide; 1: Wacker oxidation;
DOI:10.1021/ol049665m