t-BuBrettPhos Palladacycle Gen. 3

Base Information

• Chemical Name: t-BuBrettPhos Palladacycle Gen. 3
• CAS No.: 1536473-72-9
• Molecular Formula: C44H63NO5PPdS
• Molecular Weight: 855.433481
• Mol file: 1536473-72-9.mol

Synonyms:Methanesulfonato 2-Di-t-butylphosphino-3,6-dimethoxy-2'-4' -6'-tri-i-propyl-1,1'-bipheny)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)

Chemical Property of t-BuBrettPhos Palladacycle Gen. 3

Chemical Property:

• PSA: 103.67000
• LogP: 12.84500
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C

Purity/Quality:

98% ^*data from raw suppliers

[2''-(Amino-κN)[1,1''-biphenyl]-2-yl-κC][[3,6-dimethoxy-2'',4'',6''-tris(1-methylethyl)[1,1''-biphenyl]-2-yl]bis(1,1-dimethylethyl)phosphine-κP](methanesulfonato-κO)palladium(tBuBrettPhosPdG3) ^*data from reagent suppliers

Safty Information:

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MSDS Files:

Useful:

• Uses: tBuBrettPhos Pd G3 has been used as a precatalyst for the N-arylation of amino acid esters with aryl triflates under mild reaction conditions and minimal racemization of the amino acid ester. It may also be used to catalyze the conversion of aryl halides to phenols in the presence of benzaldoxime as a hydroxide surrogate.