[13C]-9-Methylfluorene-9-carbonyl chloride

Base Information

Chemical Name:[13C]-9-Methylfluorene-9-carbonyl chloride
CAS No.:1072315-89-9
Molecular Formula:C15H11ClO
Molecular Weight:243.70924
Hs Code.:
Mol file:1072315-89-9.mol

Synonyms:[13C]-9-Methylfluorene-9-carbonyl chloride;13COgen;9-Methyl-9H-fluorene-9-carbonyl-13C chloride

Suppliers and Price of [13C]-9-Methylfluorene-9-carbonyl chloride

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
9-Methyl-9H-fluorene-9-carbonyl-13C chloride ≥97.0% (GC)
1g
$ 1090.00

Sigma-Aldrich
9-Methyl-9H-fluorene-9-carbonyl-13C chloride ≥97.0% (GC)
250mg
$ 328.00

Total 6 raw suppliers

Chemical Property of [13C]-9-Methylfluorene-9-carbonyl chloride

Chemical Property:

Flash Point:>110℃
PSA：17.07000
LogP:3.73840

Purity/Quality:

98%min ^*data from raw suppliers

9-Methyl-9H-fluorene-9-carbonyl-13C chloride ≥97.0% (GC) ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:C
Statements: 34
Safety Statements: 26-36/37/39-45

MSDS Files:: SDS file from LookChem

Useful:

Uses COGen is a simple alternative for carbon monoxide generation in the application of palladium-catalyzed carbonylation reactions. This reagent has proved to be applicable in a wide range of applications and is compatible with several building blocks in the formation of ketones, amides, esters, etc.For more information please visit: Technology Spotlight, Professor Skrystrup PPP

Technology Process of [13C]-9-Methylfluorene-9-carbonyl chloride

There total 5 articles about [13C]-9-Methylfluorene-9-carbonyl chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1285695-14-8
[(13C)]-9-methyl-9H-fluorene-9-carboxylic acid

: 1072315-89-9
9-methylfluorene-9-([⁽¹³⁾C]-carbonyl) chloride

Guidance literature:: With phosphorus pentachloride;
DOI:10.1039/b806359a

Reference yield:

: 486-25-9,952573-42-1
9-fluorenone

: 1072315-89-9
9-methylfluorene-9-([⁽¹³⁾C]-carbonyl) chloride

Guidance literature:: Multi-step reaction with 5 steps

2.1: acetic acid / Reflux

3.1: palladium on carbon; hydrogen / 760.05 Torr

4.1: n-butyllithium / tetrahydrofuran; hexane / -78 °C / Inert atmosphere

4.2: -78 - 20 °C

5.1: oxalyl dichloride; N,N-dimethyl-formamide / dichloromethane / 3 h / 30 °C / Inert atmosphere

With n-butyllithium; oxalyl dichloride; palladium on carbon; hydrogen; acetic acid; N,N-dimethyl-formamide; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1021/ja200818w

Reference yield:

: 6311-22-4
9-methyl-9H-fluoren-9-ol

: 1072315-89-9
9-methylfluorene-9-([⁽¹³⁾C]-carbonyl) chloride

Guidance literature:: Multi-step reaction with 4 steps

1.1: acetic acid / Reflux

2.1: palladium on carbon; hydrogen / 760.05 Torr

3.1: n-butyllithium / tetrahydrofuran; hexane / -78 °C / Inert atmosphere

3.2: -78 - 20 °C

4.1: oxalyl dichloride; N,N-dimethyl-formamide / dichloromethane / 3 h / 30 °C / Inert atmosphere

With n-butyllithium; oxalyl dichloride; palladium on carbon; hydrogen; acetic acid; N,N-dimethyl-formamide; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1021/ja200818w