1,2-Benzenedimethanol,-alpha-,-alpha--diethyl-,(-alpha-S,-alpha-S)-(9CI)

Base Information

Chemical Name:1,2-Benzenedimethanol,-alpha-,-alpha--diethyl-,(-alpha-S,-alpha-S)-(9CI)
CAS No.:357427-66-8
Molecular Formula:C12H18O2
Molecular Weight:194.274
Hs Code.:
Mol file:357427-66-8.mol

Synonyms:1,2-Benzenedimethanol,-alpha-,-alpha--diethyl-,(-alpha-S,-alpha-S)-(9CI)

Suppliers and Price of 1,2-Benzenedimethanol,-alpha-,-alpha--diethyl-,(-alpha-S,-alpha-S)-(9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 1 raw suppliers

Chemical Property of 1,2-Benzenedimethanol,-alpha-,-alpha--diethyl-,(-alpha-S,-alpha-S)-(9CI)

Chemical Property:

Melting Point:74.2 - 75.3 °C
PSA：40.46000
LogP:2.57340

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1,2-Benzenedimethanol,-alpha-,-alpha--diethyl-,(-alpha-S,-alpha-S)-(9CI)

There total 9 articles about 1,2-Benzenedimethanol,-alpha-,-alpha--diethyl-,(-alpha-S,-alpha-S)-(9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 1,2-bis((S)-1-(((3aS,6aS)-3a-allylhexahydro-6aH-cyclopenta[b]furan-6a-yl)oxy)propyl)benzene

: 357427-66-8,357427-68-0,85157-47-7
(S,S)-1,2-bis(1-hydroxypropyl)benzene

Guidance literature:: With toluene-4-sulfonic acid; In methanol; for 1h; Reflux;
DOI:10.1246/bcsj.20150066

Reference yield: 84.0%

: 1-[2-{1-(4-methoxybenzyloxy)propyl}]phenylpropanol

: 85157-57-9,357427-68-0,85157-47-7
meso-1,2-bis(1-hydroxypropyl)benzene

: 357427-66-8,357427-68-0,85157-47-7
(S,S)-1,2-bis(1-hydroxypropyl)benzene

Guidance literature:: With ammonium cerium(IV) nitrate; In water; acetonitrile; at 20 ℃; for 3h;
DOI:10.1246/cl.2001.1110

Reference yield:

: 6630-33-7
ortho-bromobenzaldehyde

: 357427-66-8,357427-68-0,85157-47-7
(S,S)-1,2-bis(1-hydroxypropyl)benzene

Guidance literature:: Multi-step reaction with 5 steps

1.1: (S)-2-(4-methylpiperazin-1-yl)methylindoline / cyclohexane / 20 h / 0 °C

2.1: NaH / dimethylformamide / 17 h / 20 °C

3.1: BuLi / diethyl ether / 3 h / 0 °C

3.2: diethyl ether / 3 h / 0 - 20 °C

4.1: cyclohexane / 22 h / 0 °C

5.1: 84 percent / cerium ammonium nitrite / acetonitrile; H₂O / 3 h / 20 °C

With n-butyllithium; ammonium cerium(IV) nitrate; sodium hydride; (S)-2-(4-methylpiperazin-1-ylmethyl)indoline; In diethyl ether; cyclohexane; water; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1246/cl.2001.1110