Sipeimone

Base Information

• Chemical Name: Sipeimone
• CAS No.: 61989-75-1
• Molecular Formula: C₂₇H₄₁NO₃
• Molecular Weight: 427.627
• DSSTox Substance ID: DTXSID601346716
• Mol file: 61989-75-1.mol

Synonyms:Sipeimone;(1R,6S,9S,10S,11S,14S,18S,23R,24S)-10-hydroxy-6,10,23-trimethyl-4-azahexacyclo[12.11.0.02,11.04,9.015,24.018,23]pentacosane-17,20-dione;61989-75-1;SCHEMBL24104671;DTXSID601346716;AKOS030489972

Chemical Property of Sipeimone

Chemical Property:

• PSA: 57.61000
• LogP: 4.03240
• XLogP3: 3.4
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 427.30864417
• Heavy Atom Count: 31
• Complexity: 795

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1CCC2C(C3CCC4C(C3CN2C1)CC5C4CC(=O)C6C5(CCC(=O)C6)C)(C)O
• Isomeric SMILES: C[C@H]1CC[C@H]2[C@@]([C@H]3CC[C@@H]4[C@H](C3CN2C1)C[C@H]5C4CC(=O)[C@@H]6[C@@]5(CCC(=O)C6)C)(C)O
• Description: Petitium eduardi (Rgl.) Vved yields this steroidal alkaloid which forms colourless needles from Me2CO. It has a specific rotation of [cd D - 31.7° (petroleum ether). The structure has been established from chemical and spectroscopic data and comparison with similar alkaloids from the same source.

Technology Process of Sipeimone

There total 4 articles about Sipeimone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

sipeimine (61825-98-7) → imperialone (61989-75-1)

Guidance literature:

With chromium(VI) oxide; acetic acid;

Reference yield:

Korselidine (6899-86-1,23496-41-5,23496-43-7,23496-49-3,25650-72-0,47676-29-9,47676-30-2,68736-96-9,73650-52-9,74184-79-5,85718-95-2,107299-20-7,122405-29-2,135636-54-3,147511-59-9) → korselidinedione (21858-63-9,23521-53-1,61989-75-1,73307-48-9)

Guidance literature:

With chromium(VI) oxide; In pyridine; water; for 3h; Heating;

DOI:10.1007/BF00596689

Reference yield:

→ Peiminon (21858-63-9,23521-53-1,61989-75-1,73307-48-9)

Guidance literature:

Peimin, CrO3, in Eg.;

upstream raw materials:

sipeimine

Korselidine

Refernces