bis(n,n'-di-tert-butylacetamidinato)iron(ii)

Base Information

• Chemical Name: bis(n,n'-di-tert-butylacetamidinato)iron(ii)
• CAS No.: 635680-56-7
• Molecular Formula: C₂₀H₄₂FeN₄
• Molecular Weight: 394.427
• Mol file: 635680-56-7.mol

Synonyms:Bis(N,N'-di-t-butylacetaMidinato)iron (II), Min. 98%

Chemical Property of bis(n,n'-di-tert-butylacetamidinato)iron(ii)

Chemical Property:

• Melting Point: 107°C
• PSA: 30.74000
• LogP: 4.28070
• Sensitive.: air sensitive, moisture sensitiv

Purity/Quality:

98% ^*data from raw suppliers

Bis(N,N'-di-t-butylacetamidinato)iron (II), min. 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of bis(n,n'-di-tert-butylacetamidinato)iron(ii)

There total 1 articles about bis(n,n'-di-tert-butylacetamidinato)iron(ii) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

1,3-di-tert-butylcarbodiimide (691-24-7) + methyllithium (917-54-4) + iron(II) chloride → iron bis(N,N'-di-tert-butylacetamidinate) (635680-56-7)

Guidance literature:

In tetrahydrofuran; diethyl ether; under N2 atm. soln. MeLi in Et2O was added dropwise to soln. 1,3-di-tert-butylcabodiimide in Et2O at -30°C, react. mixt. was warmed to room temp., stirred for 4 h, added to soln. FeCl2 in THF and stirred for 12 h under exclusion of light; volatiles were removed under reduced pressure, residue was extd. with hexane, filtered through Celite, recrystn. at -30°C; elem. anal.;

DOI:10.1021/ic0345424

upstream raw materials:

1,3-di-tert-butylcarbodiimide

methyllithium