GLYOXAL-BIS-(CYCLOPENTYLIMINE)

Base Information

• Chemical Name: GLYOXAL-BIS-(CYCLOPENTYLIMINE)
• CAS No.: 67430-51-7
• Molecular Formula: C₁₂H₂₀N₂
• Molecular Weight: 192.304
• Mol file: 67430-51-7.mol

Synonyms:GLYOXAL-BIS-(CYCLOPENTYLIMINE)

Chemical Property of GLYOXAL-BIS-(CYCLOPENTYLIMINE)

Chemical Property:

• PSA: 24.72000
• LogP: 3.01320

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of GLYOXAL-BIS-(CYCLOPENTYLIMINE)

There total 1 articles about GLYOXAL-BIS-(CYCLOPENTYLIMINE) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.0%

Glyoxal (131543-46-9,107-22-2) + Cyclopentamine (1003-03-8) → NCHCHN(C5H9)2 (67430-51-7)

Guidance literature:

In propan-1-ol; at 25 ℃; for 2h; Inert atmosphere; Schlenk technique;

DOI:10.1016/j.poly.2020.114870

Reference yield: 70.0%

[ReOCl3(PPh3)2] + NCHCHN(C5H9)2 (67430-51-7) → Re(OP(C6H5)3)Cl3(NCHCHN(C5H9)2) (607719-92-6)

Guidance literature:

In benzene; ligand was added to soln. of Re-complex in benzene, stirred for 30 min at room temp.; solvent was removed under reduced pressure, washed with hexane, dissolved in CH2Cl2, silica gel column chromy. with benzene, eluted with benzene-MeCN, solvent was removed under reduced pressure;

DOI:10.1021/ic034586c

upstream raw materials:

Glyoxal

Cyclopentamine

Downstream raw materials:

Re(OP(C₆H₅)3)Cl₃(NCHCHN(C₅H₉)2)