2-Chloro-3-hexylthiophene

Base Information

• Chemical Name: 2-Chloro-3-hexylthiophene
• CAS No.: 817181-75-2
• Molecular Formula: C₁₀H₁₅ClS
• Molecular Weight: 202.748
• Mol file: 817181-75-2.mol

Synonyms:2-Chloro-3-hexylthiophene

Chemical Property of 2-Chloro-3-hexylthiophene

Chemical Property:

• Refractive Index: 1.5090-1.5130
• Boiling Point: 60°C/0.2mmHg(lit.)
• PSA: 28.24000
• LogP: 4.52430
• Storage Temp.: 0-10°C

Purity/Quality:

97% ^*data from raw suppliers

2-Chloro-3-hexylthiophene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-Chloro-3-hexylthiophene

There total 3 articles about 2-Chloro-3-hexylthiophene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

3-hexylthiophene (1693-86-3) → 2-chloro-3-(n-hexyl)-thiophene (817181-75-2)

Guidance literature:

With sulfuryl dichloride; at 20 ℃; for 8h;

DOI:10.1021/jo902515z

Reference yield: 16.0%

3-hexylthiophene (1693-86-3) → 3-Hexyl-2-iodothiophene (124561-55-3) + 2-chloro-3-(n-hexyl)-thiophene (817181-75-2)

Guidance literature:

With N-chloro-succinimide; sodium iodide; In acetic acid; at 20 ℃; for 2h;

DOI:10.1016/j.tetlet.2009.12.125

Reference yield:

C15H21BClNO4S → C20H28Cl2S2 + 2-chloro-3-(n-hexyl)-thiophene (817181-75-2)

Guidance literature:

With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; In tetrahydrofuran; water; at 55 ℃;

DOI:10.1021/ma502542g

upstream raw materials:

3-hexylthiophene

Downstream raw materials:

3,4'-dihexyl-2,2'-bithiophene