Diiodo(methyl)bis(triphenylphosphine)rhodium(III)

Base Information

Chemical Name:Diiodo(methyl)bis(triphenylphosphine)rhodium(III)
CAS No.:47829-28-7
Molecular Formula:C37H34I2P2Rh
Molecular Weight:896.319882
Hs Code.:
Mol file:47829-28-7.mol

Synonyms:Diiodo(methyl)bis(triphenylphosphine)rhodium(III)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Diiodo(methyl)bis(triphenylphosphine)rhodium(III)

Chemical Property:

PSA：27.18000
LogP:8.09330

Purity/Quality:

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Technology Process of Diiodo(methyl)bis(triphenylphosphine)rhodium(III)

There total 1 articles about Diiodo(methyl)bis(triphenylphosphine)rhodium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 88825-75-6
(P(C₆H₅)3)3Rh⁽¹⁺⁾*(HC(SO₂CF₃)2)^(1-)=P₃(C₆H₅)9RhHC(SO₂CF₃)2

: 47829-28-7
Rh(P(C₆H₅)3)2(CH₃)I₂

Guidance literature:: With CH₃I; In dichloromethane; CH2Cl2 (15 mL) and CH3I (0.4 mL) condensed onto the Rh salt (1.2 g; warming to room temp.; stirring (3 h); volatiles removed (pumping); twice recrystn. in air (butanone/CH2Cl2); elem. anal.; mol wt. 874 (vapor pressure osmometry in CHCl3);

Reference yield: 78.0%

: 47829-28-7
Rh(P(C₆H₅)3)2(CH₃)I₂

: 89579-42-0
Rh(P(C₆H₅)3)(CH₃)(C₅H₅N)2I₂

Guidance literature:: With pyridine; In dichloromethane; pyridine (4 drops) added to Rh compd. (0.13 mmol) in CH2Cl2; ethanol added; soln. concd. (vac.) giving powder (= 2.6 : 1 mixt. of 2 isomers); elem. anal.;

Reference yield: 71.0%

: 47829-28-7
Rh(P(C₆H₅)3)2(CH₃)I₂

: 89596-64-5
Rh(P(C₆H₅)3)2(SO₂CH₃)I₂

Guidance literature:: With SO₂; In benzene; SO2 slowly passed through stirred suspn. of Rh compd. in N2-satd. benzene (20 min); react. mechanism discussed; to resulting soln., n-octane added to the cloud point; filtratiuon; filtrate concd. (rotatory evaporator) providing small crystals; elem. anal.;