ruthenium(2+) trifluoroacetate - [3-{bis[3-(trifluoromethyl)phenyl]phosphanyl}-2-({bis[3-(trifluoromethyl)phenyl]phosphanyl}methyl)-2-methylpropyl]{bis[3-(trifluoromethyl)phenyl]}phosphane (1:2:1)

Base Information

• Chemical Name: ruthenium(2+) trifluoroacetate - [3-{bis[3-(trifluoromethyl)phenyl]phosphanyl}-2-({bis[3-(trifluoromethyl)phenyl]phosphanyl}methyl)-2-methylpropyl]{bis[3-(trifluoromethyl)phenyl]}phosphane (1:2:1)
• CAS No.: 249631-03-6
• Molecular Formula: C₅₁H₃₃F₂₄O₄P₃Ru
• Molecular Weight: 1359.77
• Mol file: 249631-03-6.mol

Synonyms:

Chemical Property of ruthenium(2+) trifluoroacetate - [3-{bis[3-(trifluoromethyl)phenyl]phosphanyl}-2-({bis[3-(trifluoromethyl)phenyl]phosphanyl}methyl)-2-methylpropyl]{bis[3-(trifluoromethyl)phenyl]}phosphane (1:2:1)

Chemical Property:

• Vapor Pressure: 1.16E-21mmHg at 25°C
• Boiling Point: 753.1°Cat760mmHg
• Flash Point: 409.2°C
• Density: g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of ruthenium(2+) trifluoroacetate - [3-{bis[3-(trifluoromethyl)phenyl]phosphanyl}-2-({bis[3-(trifluoromethyl)phenyl]phosphanyl}methyl)-2-methylpropyl]{bis[3-(trifluoromethyl)phenyl]}phosphane (1:2:1)

There total 1 articles about ruthenium(2+) trifluoroacetate - [3-{bis[3-(trifluoromethyl)phenyl]phosphanyl}-2-({bis[3-(trifluoromethyl)phenyl]phosphanyl}methyl)-2-methylpropyl]{bis[3-(trifluoromethyl)phenyl]}phosphane (1:2:1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.2%

CH3C(CH2P(C6H4CF3)2)3 (204906-16-1) + [Ru2(cyclo-octa-1,5-diene)2(H2O)(CF3CO2)4] → Ru(CF3SO3)2(CH3C(CH2P(m-CF3C6H4)2)3) (249631-03-6,207747-32-8)

Guidance literature:

In diethyl ether; byproducts: H2O, COD; Ar-atmosphere; dropwise addn. of Ru-complex to 2 equiv. of phosphine at room temp., stirring (room temp., overnight); pptn. on hexane addn., filtration, washing (hexane), drying (vac.); elem. anal.;

Reference yield: 73.4%

Ru(CF3SO3)2(CH3C(CH2P(m-CF3C6H4)2)3) (249631-03-6,207747-32-8) + trifluorormethanesulfonic acid (1493-13-6) + acetonitrile (75-05-8,26809-02-9) → [Ru(MeCN)3(CH3C(CH2P(m-CF3C6H4)2)3)](CF3SO3)2 (207747-34-0)

Guidance literature:

In acetonitrile; Ar-atmosphere; dropwise addn. of 4 equiv. CF3SO3H to Ru-complex soln. atroom temp., stirring (room temp., 1 h); concn. (reduced pressure), addn. of Et2O, then addn. of hexane (pptn.), filtration, washing (Et2O), drying (vac.); elem. anal.;

Reference yield: 64.6%

hydrogenchloride (7647-01-0,15364-23-5) + Ru(CF3SO3)2(CH3C(CH2P(m-CF3C6H4)2)3) (249631-03-6,207747-32-8) → [Ru2(μ-Cl)3(CH3C(CH2P(m-CF3C6H4)2)3)2]Cl (249631-12-7)

Guidance literature:

In chloroform; byproducts: CF3COOH; Ar-atmosphere; dropwise addn. of 37% HCl to Ru-complex soln. at room temp., stirring (room temp., 2 h); neutralization (Na2CO3), addn. of H2O, drying of org. layer (Na2SO4), filtration, concn. (reduced pressure), pptn. on hexane addn., filtration, washing (hexane), drying (vac.); elem. anal.;

upstream raw materials:

CH₃C(CH₂P(C₆H₄CF₃)2)3

Downstream raw materials:

[Ru(MeCN)3(CH₃C(CH₂P(m-CF₃C₆H₄)2)3)](CF₃SO₃)2

[Ru2(μ-Cl)3(CH3C(CH2P(m-CF3C6H4)2)3)2]Cl

[RuH(MeCN)2(CH₃C(CH₂P(m-CF₃C₆H₄)2)3)]CF₃SO₃

Refernces