6-Methyl-2-(4-vinylphenyl)-1,3,6,2-dioxazaborocane-4,8-dione

Base Information

Chemical Name:6-Methyl-2-(4-vinylphenyl)-1,3,6,2-dioxazaborocane-4,8-dione
CAS No.:1257648-79-5
Molecular Formula:C13H14BNO4
Molecular Weight:259.06556
Hs Code.:
Mol file:1257648-79-5.mol

Synonyms:4-Vinylphenylboronic acid MIDA ester;6-Methyl-2-(4-vinylphenyl)-1,3,6,2-dioxazaborocane-4,8-dione;4-Vinylphenylboronic acid MIDA ester 97%

Suppliers and Price of 6-Methyl-2-(4-vinylphenyl)-1,3,6,2-dioxazaborocane-4,8-dione

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
4-Vinylphenylboronic acid MIDA ester 97%
5g
$ 190.00

American Custom Chemicals Corporation
4-VINYLPHENYLBORONIC ACID MIDA ESTER 95.00%
1G
$ 753.72

American Custom Chemicals Corporation
4-VINYLPHENYLBORONIC ACID MIDA ESTER 95.00%
500MG
$ 633.91

Total 9 raw suppliers

Chemical Property of 6-Methyl-2-(4-vinylphenyl)-1,3,6,2-dioxazaborocane-4,8-dione

Chemical Property:

Melting Point:198-204 °C
PSA：55.84000
LogP:-0.00550

Purity/Quality:

98%,99%, ^*data from raw suppliers

4-Vinylphenylboronic acid MIDA ester 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xn
Statements: 22

MSDS Files:: SDS file from LookChem

Useful:

Uses Suzuki Cross-Coupling with MIDA Boronates

Technology Process of 6-Methyl-2-(4-vinylphenyl)-1,3,6,2-dioxazaborocane-4,8-dione

There total 2 articles about 6-Methyl-2-(4-vinylphenyl)-1,3,6,2-dioxazaborocane-4,8-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: C₁₃H₁₆BNO₄

: 1257648-79-5
6-methyl-2-(4-vinylphenyl)-1,3,6,2-dioxazaborocane-4,8-dione

Guidance literature:: With 2-chloroanthracene-9,10-dione; cobalt(II) diacetate tetrahydrate; butane-2,3-dione dioxime; In 1,2-dichloro-ethane; at 20 - 30 ℃; for 36h; Irradiation; Schlenk technique; Sealed tube; Inert atmosphere;
DOI:10.1021/jacs.1c05479

Reference yield: 74.0%

: 4408-64-4
N-methyliminodiacetic acid

: 2156-04-9,593231-72-2
4-Vinylphenylboronic acid

: 1257648-79-5
6-methyl-2-(4-vinylphenyl)-1,3,6,2-dioxazaborocane-4,8-dione

Guidance literature:: In dimethyl sulfoxide; benzene; at 80 ℃; for 16h; Inert atmosphere;
DOI:10.1021/acs.joc.8b00402

Reference yield: 59.0%

: 870004-04-9
4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)styrene

: 1257648-79-5
6-methyl-2-(4-vinylphenyl)-1,3,6,2-dioxazaborocane-4,8-dione

: 1382249-93-5,1034917-77-5
(E)-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan)-4'-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)stilbene

: (E)-2,2'-(4,4'-(ethene-1,2-diyl)bis(4,1-phenylene))bis(6-methyl-1,3,6,2-dioxazaborocane-4,8-dione)

: (E)-6-methyl-2-(4-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)styryl)phenyl)-1,3,6,2-dioxazaborocane-4,8-dione

Guidance literature:: With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In dichloromethane; at 43 ℃; for 16h; Inert atmosphere;
DOI:10.1016/j.tetlet.2012.12.081