Methyl 3,6-Dideoxy-α-D-arabino-hexopyranoside

Base Information

• Chemical Name: Methyl 3,6-Dideoxy-α-D-arabino-hexopyranoside
• CAS No.: 6154-71-8
• Molecular Formula: C7H14O4
• Molecular Weight: 162.18366
• Mol file: 6154-71-8.mol

Synonyms:Methyl 3,6-Dideoxy-α-D-arabino-hexopyranoside;Methyl 3,6-dideoxy-a-D-arabino-hexopyranoside

Chemical Property of Methyl 3,6-Dideoxy-α-D-arabino-hexopyranoside

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Boiling Point: 296.386°C at 760 mmHg
• Flash Point: 133.05°C
• PSA: 58.92000
• Density: 1.192g/cm³
• LogP: -0.51050
• Solubility.: Dichloromethane, Dichloromethane

Purity/Quality:

96% ^*data from raw suppliers

Methyl 3,6-dideoxy-a-D-arabino-hexopyranoside ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: An intermediate in the preparation of Tyvelose

Technology Process of Methyl 3,6-Dideoxy-α-D-arabino-hexopyranoside

There total 11 articles about Methyl 3,6-Dideoxy-α-D-arabino-hexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

methyl 4-O-benzoyl-3,6-dideoxy-α-D-arabino-hexopyranoside (58056-38-5) → methyl 3,6-dideoxy-β-D-arabino-hexopyranoside (6109-62-2) + methyl 3,6-dideoxy-α-D-arabino-hexopyranoside (6154-71-8)

Guidance literature:

With sodium methylate; In methanol; for 2h; Ambient temperature;

DOI:10.1016/S0008-6215(96)00229-7

Reference yield: 82.0%

methyl 3,6-dideoxy-2-O-(methylthio)carbonyl-α-D-arabino-hexopyranoside (74969-47-4) → methyl 3,6-dideoxy-α-D-arabino-hexopyranoside (6154-71-8)

Guidance literature:

With methanol; sodium; for 1h;

Reference yield: 5.6%

methyl 3,6-di-O-pivaloyl-α-D-mannopyranoside (86651-41-4) → methyl 3,6-dideoxy-α-D-arabino-hexopyranoside (6154-71-8) + methyl 3-deoxy-6-O-pivaloyl-α-D-arabino-hexopyranoside (86651-46-9) + methyl 6-deoxy-3-O-pivaloyl-α-D-mannopyranoside (86670-19-1)

Guidance literature:

In N,N,N,N,N,N-hexamethylphosphoric triamide; water; for 168h; Irradiation;

DOI:10.1016/0008-6215(83)88119-1

upstream raw materials:

methyl 3,6-dideoxy-2-O-(methylthio)carbonyl-α-D-arabino-hexopyranoside

methyl 3,6-di-O-pivaloyl-α-D-mannopyranoside

methyl 4-O-benzoyl-3,6-dideoxy-α-D-arabino-hexopyranoside

(2R,3S,4S,5S,6S)-2-(hydroxymethyl)-6-methoxytetrahydro-2H-pyran-3,4,5-triol

Downstream raw materials:

methyl 2-O-benzoyl-5-O-benzyl-3,6-dideoxy-α-D-arabino-hexofuranoside

methyl 2,4-di-O-benzyl-α-D-tyvelopyranoside

methyl-5-O-benzyl-3,6-didesoxy-2-O-tosyl-α-D-arabino-hexofuranoside

methyl-2-azido-5-O-benzyl-2,3,6-tridesoxy-α-D-ribo-hexofuranoside