3-(4-BIPHENYL)-2-METHYL-1-PROPENE

Base Information

• Chemical Name: 3-(4-BIPHENYL)-2-METHYL-1-PROPENE
• CAS No.: 53573-00-5
• Molecular Formula: C16H16
• Molecular Weight: 208.303
• Hs Code.: 2902909090
• Mol file: 53573-00-5.mol

Synonyms:3-(4-BIPHENYL)-2-METHYL-1-PROPENE

Chemical Property of 3-(4-BIPHENYL)-2-METHYL-1-PROPENE

Chemical Property:

• Vapor Pressure: 0.000616mmHg at 25°C
• Boiling Point: 319.9°C at 760 mmHg
• Flash Point: 153.4°C
• PSA: 0.00000
• Density: 0.966g/cm³
• LogP: 4.47220

Purity/Quality:

97% ^*data from raw suppliers

3-(4-Biphenyl)-2-methyl-1-propene 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-(4-BIPHENYL)-2-METHYL-1-PROPENE

There total 1 articles about 3-(4-BIPHENYL)-2-METHYL-1-PROPENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

2-methallyltrimethylsilane (18292-38-1) + 4-iodo-biphenyl (1591-31-7) → biphenyl (92-52-4,1594-86-1) + 4-(2-methylprop-2-en-1-yl)biphenyl (53573-00-5)

Guidance literature:

With cesium fluoride; In acetonitrile; at -78 - 25 ℃; for 24h; Irradiation; Sealed tube; Inert atmosphere;

DOI:10.1021/acs.orglett.0c03935

Reference yield: 52.0%

4-(2-methylprop-2-en-1-yl)biphenyl (53573-00-5) + 4-[2-(4-fluorophenylsulfonyl)acetyl]benzonitrile (1313054-92-0) → 4-(5-([1,1'-biphenyl]-4-ylmethyl)-3-((4-fluorophenyl)sulfonyl)-5-methyl-4,5-dihydrofuran-2-yl)benzonitrile

Guidance literature:

With copper diacetate; manganese(III) triacetate dihydrate; acetic acid; at 80 ℃; Microwave irradiation;

DOI:10.1016/j.ejmech.2018.02.029

Reference yield:

4-(2-methylprop-2-en-1-yl)biphenyl (53573-00-5) + 4-[2-(4-fluorophenylsulfonyl)acetyl]benzonitrile (1313054-92-0) → 4-(5-([1,1'-biphenyl]-4-ylmethyl)-3-((4-fluorophenyl)sulfonyl)-5-methyl-4,5-dihydrofuran-2-yl)-N'-hydroxybenzimidamide

Guidance literature:

Multi-step reaction with 2 steps

1: manganese(III) triacetate dihydrate; copper diacetate; acetic acid / 80 °C / Microwave irradiation

2: hydroxylamine hydrochloride; potassium tert-butylate / dimethyl sulfoxide / Inert atmosphere

With hydroxylamine hydrochloride; potassium tert-butylate; copper diacetate; manganese(III) triacetate dihydrate; acetic acid; In dimethyl sulfoxide;

DOI:10.1016/j.ejmech.2018.02.029

upstream raw materials:

2-methallyltrimethylsilane

4-iodo-biphenyl

Refernces