Technology Process of Carbamic acid, (2-fluoro-1,2-dimethylpropyl)-, 1,1-dimethylethyl ester (9CI)
There total 5 articles about Carbamic acid, (2-fluoro-1,2-dimethylpropyl)-, 1,1-dimethylethyl ester (9CI) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
hydrogen; triethylamine;
palladium dihydroxide;
In
ethanol;
for 20h;
under 2585.81 Torr;
DOI:10.1021/jo000242h
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 6.34 g / CHCl3 / 4 h / 20 °C
2: 3.46 g / iodine; triphenylphosphinie polystyryl-supported; imidazole / CH2Cl2 / 2 h / Heating
3: 1.80 g / hydrogen; triethylamine / palladium(II) hydroxide / ethanol / 20 h / 2585.81 Torr
With
1H-imidazole; triphenylphosphinie polystyryl-supported; hydrogen; iodine; triethylamine;
palladium dihydroxide;
In
ethanol; dichloromethane; chloroform;
1: Substitution / 2: Substitution / 3: Hydrogenolysis;
DOI:10.1021/jo000242h
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 3.83 g / lithium borohydride; trimethylsilyl chloride / tetrahydrofuran / 24 h
2: 6.34 g / CHCl3 / 4 h / 20 °C
3: 3.46 g / iodine; triphenylphosphinie polystyryl-supported; imidazole / CH2Cl2 / 2 h / Heating
4: 1.80 g / hydrogen; triethylamine / palladium(II) hydroxide / ethanol / 20 h / 2585.81 Torr
With
1H-imidazole; lithium borohydride; chloro-trimethyl-silane; triphenylphosphinie polystyryl-supported; hydrogen; iodine; triethylamine;
palladium dihydroxide;
In
tetrahydrofuran; ethanol; dichloromethane; chloroform;
1: Reduction / 2: Substitution / 3: Substitution / 4: Hydrogenolysis;
DOI:10.1021/jo000242h
